Systematic and random errors in a photoelectric effect experiment can significantly impact results, particularly when measuring the stopping voltage against photon frequency. Key sources of error include calibration drift, hysteresis, and potential inaccuracies in the photodiode's response to varying light frequencies. Environmental factors, such as temperature fluctuations and electromagnetic interference, may also affect measurements. The experiment's design and apparatus specifics are crucial for identifying additional error sources. Understanding these factors is essential for accurately comparing experimental values of Planck's constant to established ones.