Power Series Solution to Hydrogen Wave Function Differential Equation

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Homework Help Overview

The discussion revolves around solving the differential equation related to the theta portion of the hydrogen wave function using a power series solution. Participants are exploring the implications of their findings and the normalization conditions associated with Legendre polynomials.

Discussion Character

  • Exploratory, Conceptual clarification, Mathematical reasoning, Assumption checking

Approaches and Questions Raised

  • Participants discuss the application of a recursion formula derived from the power series solution and question whether substituting specific values for l directly yields valid solutions. There is also inquiry into the normalization process for the Legendre polynomials.

Discussion Status

Some participants have provided guidance on the normalization condition for Legendre polynomials, noting that it differs from typical normalization methods. There is ongoing exploration of the implications of setting l to specific values and the resulting coefficients.

Contextual Notes

Participants are navigating the constraints of the problem, including the normalization condition P_L(1)=1 and the implications of truncating the power series. There is uncertainty regarding the necessity of normalization in this context.

eku_girl83
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I solved the differential equation for theta portion of the hydrogen wave function using a power series solution. I got a sub n+2 = a sub n ((n(n+1)-C)/(n+2)(n+1)). I then truncated the power series at n = l to get
C= l(l+1).

I know need to use the recursion formula I found to find the l = 0, 1, 2, and 3 solutions to the differential equation. Do I simply plug l in for n? If so, I get for l = 0, a2 = -Ca0/2. Is this the SOLUTION to the D.E. for
l = 0, or do I need to do something else?
Similarly, for l = 1, I get a3= a1 (2-C)/6.

Any help appreciated!
 
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Put in C=L(L+1) and do the arith.
The last step is to require P_L(1)=1, which is the normalization conditon for Legendre polynomials (the name of the theta solutions).
 
If I sub in C= L(L+1), then I get a2 = -l(l+1)a0/2. But this is the solution for l = 0...so if I let l = 0, then I get a2 =0. This is also true for a3, a4, a5, ... Is this ok?

Also...when I normalize...Do I do the integral of a2^2 from -1 to 1 = 1 (since x = cos theta) and solve for a0??

I'm just a bit confused...thanks!
 
eku_girl83 said:
If I sub in C= L(L+1), then I get a2 = -l(l+1)a0/2. But this is the solution for l = 0...so if I let l = 0, then I get a2 =0. This is also true for a3, a4, a5, ... Is this ok?
Yes. For any L, the solution is a poynomial of degree L.
For L=0, P_0=1. For L_1. P_1=1, etc.
 
eku_girl83 said:
Also...when I normalize...Do I do the integral of a2^2 from -1 to 1 = 1 (since x = cos theta) and solve for a0??
QUOTE]
The usual Legendre polynomials are normalized so that P_L(1)=1 for each value of L. No integral is involved. This is different (and easier) than the usual normalization of functions. For your problem, the normalization may not be necessary.
 
eku_girl83 said:
I'm just a bit confused...thanks!
It may be time to look in a Math Physics book under
Legendre Polynomials in the index.
 

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