sridhar
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Homework Statement
Determine approximately the ground state energy of a helium like atom using first order perturbation theory in the electron-electron interaction.
Ignore the spins of the electrons and the Pauli principle.
Homework Equations
given that \intd\tau1\intd\tau2 e^-(r1+r2){}/r1+r2 = 20\Pi^{2}
The Attempt at a Solution
Consider a system where electron1-electron2 distance = r12
electron1-nucleus distance= r1
electron2-nucleus distance= r2
The S.E of this system would be exactly solvable if the term containing r12 disappears from the hamiltonian. Therefore we treat k/(r12)^{2} as the perturbation!
I applied the first order perturbation for the term k/r12
the correction would basically be <\Psi /k/(r12)^{2} / \Psi>
And i am stuck! Cant understand what to do next!