Prove Heisenberg Uncertainty Principle for Ground State Harmonic Oscillator

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Discussion Overview

The discussion revolves around proving the Heisenberg Uncertainty Principle for the ground state of a harmonic oscillator using expectation values. Participants explore the mathematical derivation involving wave functions, integrals, and operators, while addressing specific challenges in calculations.

Discussion Character

  • Technical explanation
  • Mathematical reasoning
  • Debate/contested

Main Points Raised

  • One participant presents the ground state wave equation and attempts to calculate expectation values, noting difficulties in finding .
  • Another participant suggests using the Hamiltonian to relate , , and to simplify the problem.
  • Concerns are raised about the calculation of , with one participant consistently obtaining zero, despite knowing it should not be.
  • Participants discuss the proper application of the expectation value equation and the order of operations in derivatives and integrals.
  • Clarifications are made regarding the treatment of wave functions under the momentum operator, emphasizing that the operator should only act on the second wave function in the expectation value equation.
  • One participant expresses frustration over a mistake in the order of operations, which led to confusion in calculations.

Areas of Agreement / Disagreement

There is no consensus on the resolution of the calculation issues, as participants are still working through the mathematical details and addressing misunderstandings. Multiple viewpoints on the correct approach to the problem are present.

Contextual Notes

Participants note the importance of normalization of the wave function and the need to ensure proper application of mathematical operations in the context of quantum mechanics.

Who May Find This Useful

Readers interested in quantum mechanics, particularly those studying the harmonic oscillator and the Heisenberg Uncertainty Principle, may find this discussion relevant.

Sciencenerd3
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Ground State Wave Equation:
ψ0=(a/∏)(1/4)e(-ax2/2)

Prove the Heisenberg Uncertainty principle ≥h(bar)/2 by way of expectation values.

First I found <x>=0 because it was an odd function

then I found <Px>=0 because it was an odd function

Then <x2>=∫(a/∏)(1/2)x2e(-ax2)/2dx=1/2a by way of even function integral table

The problem I am having difficulty on is finding <Px2>
It involves taking the double derivative and then integrating using a table (for me). I need to go through all of the derivatives and integrals I believe in order to get things to cancel so that only h/2 will be left over but I keep getting 0 for <Px2>

I have literally been trying to work this out for ≈4-5 hrs so any help anyone can offer would be extremely appreciated.
 
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Here's a shortcut: H = p^2/2m + 1/2 m w^2 x^2, so <H> = (1/2m)<p^2> + (mw^2/2)<x^2>. You know <H> and <x^2>, so you can solve for <p^2>.
 
This seems as though it would work but I have to solve it in a specific way. My answer would be close if too many things were not cancelling but I cannot seem to work it out fully. After I integrate after taking the double derivative and keeping in mind to used the product rule, I am getting zero.
 
As far as I understand you simply are supposed to calculate [itex]\langle x \rangle[/itex], [itex]\langle p \rangle[/itex], [itex]\langle x^2 \rangle[/itex], [itex]\langle p^2 \rangle[/itex]. Since you've given the wavefunction in position space, you simply have to use the operators
[tex]\hat{x}=x, \quad \hat{p}=-\mathrm{i} \hbar \partial_x[/tex]
and use the general equation for expectation values
[tex]\langle A \rangle=\int_{\mathbb{R}} \mathrm{d} x \; \psi^*(x) \hat{A} \psi(x).[/tex]
Of course you must also check that the wave function is normalized properly, i.e., that
[tex] \int_{\mathbb{R}} \mathrm{d} x \; |\psi(x)|^2=1.[/tex]
 
Yes, the wavefunction is normalized because it is the ground state harmonic oscillator wavefunction. However, when I try to use the expectation value equation:

⟨A⟩=∫ℝdxψ∗(x)Aˆψ(x).

I get <P2>=h2(bar)/i2[-2a+2a]=0. However, I know that this value is not 0.

I am supposed to use the expectation equation and values to get Δx and Δp and show ΔxΔp≥h(bar)/2.

Uncertainty: Δx=√(<x2>-<x>2) but <x>=0. This is a similar result for Δp because <p>=0 as well.

Then after this you should be able to multiply both uncertainty values to get the Heisenberg uncertainty. But not matter what I do I can not get the expectation value of <p2> not to equal zero. And I also get <x2>=1/2a.

Is there anyone who can run through the expectation of momentum squared. It involves taking the double derivative and then integrating over allspace for the given wavefunction:

ψ0=(a/∏)(1/4)e(-ax2/2)
 
[itex]\psi_0=(\frac{\alpha}{\pi})^\frac{1}{4}e^{-\frac{\alpha x^2}{2}}[/itex]

So using the expectation equation:

[itex]<p^2>=∫\psi_0^*\hat{p}\hat{p}\psi_0dx[/itex]

[itex]<p^2>=∫\psi_0^*\frac{\hbar^2}{i^2}\frac{∂^2}{∂x^2}\psi_0dx[/itex]

[itex]<p^2>=∫\frac{\hbar^2}{i^2}\frac{∂^2}{∂x^2}(\frac{ \alpha}{\pi})^\frac{1}{2}e^{-\alpha x^2}[/itex]

[itex]\frac{∂^2}{∂x^2}(\frac{ \alpha}{\pi})^\frac{1}{2}e^{-\alpha x^2}=\frac{∂}{∂x}((\frac{ \alpha}{\pi})^\frac{1}{2}\cdot-2\alpha xe^{-\alpha x^2})=(\frac{ \alpha}{\pi})^\frac{1}{2}\cdot-2\alpha e^{-\alpha x^2}+(\frac{ \alpha}{\pi})^\frac{1}{2}\cdot4\alpha^2x^2 e^{-\alpha x^2}[/itex]

[itex]\int_{-∞}^∞e^{-\alpha x^2}=(\frac{\pi}{\alpha})^{\frac{1}{2}}[/itex]

[itex]2\cdot\int_0^∞x^2e^{-\alpha x^2}=(\frac{\pi}{\alpha})^{\frac{1}{2}}\cdot\frac{2}{4\alpha}[/itex]

So putting these values in for the integrals, I get:

[itex]<p^2>=\int_{-∞}^∞[(\frac{ \alpha}{\pi})^\frac{1}{2}\cdot-2\alpha e^{-\alpha x^2}+(\frac{ \alpha}{\pi})^\frac{1}{2}\cdot4\alpha^2x^2 e^{-\alpha x^2}]=\frac{\hbar^2}{i^2}[-2\alpha+2\alpha]=0[/itex]

I cannot figure out if I'm doing the derivatives wrong or the integrals or neither. Maybe my values from the integral tables were figured incorrectly. Whatever it is, it has evaded my solving for a long time now.
 
Could it be that I am acting on both wave functions multiplied together with the momentum operator instead of just the second wave function in the expectation equation?
 
Here's the wrong step

Sciencenerd3 said:
[itex]<p^2>=∫\psi_0^*\frac{\hbar^2}{i^2}\frac{∂^2}{∂x^2}\psi_0dx[/itex]

[itex]<p^2>=∫\frac{\hbar^2}{i^2}\frac{∂^2}{∂x^2}(\frac{ \alpha}{\pi})^\frac{1}{2}e^{-\alpha x^2}[/itex]

The first equation is OK, but then you move ψ* from the left of the differential operator to the right, such that ∂x² is no longer acting on ψ but on |ψ|².

But

[tex]\int_{-\infty}^{+\infty}dx\, \psi^\ast \frac{\partial^2}{\partial x^2} \psi \neq \int_{-\infty}^{+\infty}dx\, \frac{\partial^2}{\partial x^2} |\psi|^2[/tex]

This integral is zero (trvially) b/c

[tex]\int_{-\infty}^{+\infty}dx\, \frac{\partial^2}{\partial x^2} |\psi|^2 = \left. \frac{\partial}{\partial x} |\psi|^2\right|_{-\infty}^{+\infty} = 0[/tex]

which vanishes due to the asymptotics of ψ.

What you can do is

[tex]\int_{-\infty}^{+\infty}dx\, \psi^\ast \frac{\partial^2}{\partial x^2} \psi = - \int_{-\infty}^{+\infty}dx\, \left( \frac{\partial}{\partial x} \psi^\ast\right) \left( \frac{\partial}{\partial x} \psi\right) = \int_{-\infty}^{+\infty}dx\, \left( \frac{\partial}{\partial x} \psi\right)^2[/tex]

where I first used integration by parts (which is always OK for wave functions vanishing at infinity) and then ψ* = ψ (which holds only in special cases).
 
  • #10
Sciencenerd3 said:
Could it be that I am acting on both wave functions multiplied together with the momentum operator instead of just the second wave function in the expectation equation?

That's your problem... ##\partial^2 / \partial x^2## applies only to ##\psi_0##, not to ##\psi_0^*##:

$$\langle p^2 \rangle = \int {(\psi_0^*) \left( -\hbar^2 \frac{\partial^2 \psi_0}{\partial x^2} \right) dx}$$

(I see tom.stoer beat me to it while I was debugging my LaTeX.)
 
  • #11
Thanks so much. i cannot believe I wasted so much time on something so simple and trivial like forgetting order of operations. I'm new to the forum, is there any specific way I am supposed to give thanks or credit?
 
  • #12
We'll consider it given. At least I will... maybe Tom will have a special request like a bottle of beer or something. :smile:
 
  • #13
in such cases a bottle of whisky would be appropriate
 

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