Question about a cubic crystal and its parameters

AI Thread Summary
The discussion revolves around solving a cubic crystal problem related to the CsCl structure, where the user initially calculated the parameter 'a' as 0.14 nm but found the expected answer to be 0.124 nm. The calculation involved finding the diagonal of the square and determining the radius of A. Participants highlighted that the crystal structure features Cl- forming a cubic lattice while Cs+ occupies the body centers. A suggestion was made to use the radius ratio for cubic voids to refine the calculation. Ultimately, the user successfully arrived at the correct answer by adjusting their approach based on the provided hints.
Clara Chung
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Homework Statement


27.png


Homework Equations

The Attempt at a Solution


28.png

So i got the answer by finding the diagonal of the square and then find the radius of A.
([(2x0.17)2 ]x2 )1/2 = 2a + 2x0.17
And find out a= 0.14 nm , however the answer is 0.124nm, please help
 

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I think this is a 3D problem.
 
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Clara Chung said:

Homework Statement


View attachment 224603

Homework Equations

The Attempt at a Solution


View attachment 224604
So i got the answer by finding the diagonal of the square and then find the radius of A.
([(2x0.17)2 ]x2 )1/2 = 2a + 2x0.17
And find out a= 0.14 nm , however the answer is 0.124nm, please help
The number of nearest neighbors are 8, it is CsCl structure:

upload_2018-4-24_18-4-14.png

In your drawing, the number of nearest neighbors are 6.
 

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Clara Chung said:

Homework Statement


View attachment 224603

Homework Equations

The Attempt at a Solution


View attachment 224604
So i got the answer by finding the diagonal of the square and then find the radius of A.
([(2x0.17)2 ]x2 )1/2 = 2a + 2x0.17
And find out a= 0.14 nm , however the answer is 0.124nm, please help
Yes, the crystal structure can be simply identified identical to the CsCl where Cl- forms a cubic lattice and Cs+ occupies the body centers(cubic voids). Now you can easily use the radius ratio(r+/r-) for cubic void(here for smallest value of A use lower limit of the radius ratio range) to find out the radius of A
hint: here it is assumed that B forms the lattice and A occupies the voids
Hope that helps... [emoji4]
images%20(1).jpeg
 

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Thanks everyone for the pictures and information. I got the answer by using the diagonal of the cube. [[3x(2x0.17)2]1/2 - 2x(0.17)]/2 = 0.124
 
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