OK - to avoid having to squint at the attachment - and so others can have easier input:
$$DC_sAt = A\left ( C_0-\frac{C_s}{2} \right )\frac{x^{\prime 2}}{2} -\frac{c}{6}\left ( C_0-\frac{7}{6}C_s \right )x^{\prime 3} \qquad \text{...(23)}\\
\text{...from eqn(17), $\phi$ as a function of $x^\prime$ is obtained as follows:}\\
\phi = \frac{ADC}{x^\prime + \frac{cx^{\prime 3}}{2A}}=\frac{ADC_s}{x^\prime}-\frac{cDC_s}{2} \qquad \text{...(24)}\\
\text{...from eqn(23), $1/x^\prime$ as a function of $t$ is obtained:}\\
\text{Put $x^\prime=1/q$ into eqn(27) then:}\\
\frac{2DC_s tq^3}{C_0-\frac{C_s}{2}}=q-\frac{c}{3A}\frac{C_0-\frac{7}{6}C_s}{C_0-\frac{C_s}{2}}\qquad \text{...(25)}\\
\text{Since one is only interested in approximate solutions for a short time,}\\ \text{ the following equation:}\\
q=\left ( \frac{2DC_st}{C_0-\frac{C_s}{2}}\right )^{-1/2}+\delta \qquad \text{...(26)}\\
\text{... may be substituted into eqn(25) to give:}\\
\delta = -\frac{c}{6A}\frac{C_0-\frac{7}{6}C_s}{C_0-\frac{C_s}{2}}\qquad \text{...(27)}\\
\text{if eqn(27) is substituted into eqn(26), and eqn(26) is further substituted into eqn(24),}\\ \text{ one obtains:}\\
\phi = A\left [ DC_s\left ( C_0-\frac{C_s}{2} \right )\frac{1}{2t} \right ]^{1/2} -\frac{4}{9}cDC_s\frac{3C_0-2C_s}{2C_0-C_s}\qquad \text{...(28)}
$$
... so it is eqn 26 that is tricky?
The idea is to approximate for small time frames.
The form of the equation 25 is ##\alpha q^3 = q - \beta## ... which is a cubic equation.
Solve it for q, without making an approximation and compare.
They appear to have approximated it as ##(q-\delta)^2 = \alpha## and that delta is a parameter to be fitted.
Note: between eqn (24) and (25), there is a reference to eqn(27) which I suspect is a typo.