Specific heat capacity of calorimeter

AI Thread Summary
The discussion revolves around calculating the heat capacity of a calorimeter when a copper piece is placed in water. The specific heat capacities for copper and water are provided, and the heat transfer equations are established based on the first law of thermodynamics. The key question is whether the heat capacity of the calorimeter should be calculated with respect to the water's temperature or if it varies under different conditions. It is clarified that the calorimeter and water are assumed to be in thermal equilibrium initially, and if no water is present, the initial temperature of the calorimeter must be known. The conversation emphasizes the importance of understanding heat transfer principles in calorimetry.
Pouyan
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I've got a problem:
A piece of copper with mass m1 = 800 g and temperature t1 = 80 ° C is placed in a container with good thermal insulation. The vessel initially contains water with mass m2 = 500 g temperature t2 = 20 C. What is the calorimeter (including thermo meter) heat capacity if the end temperature is tf = 26 C?!

The solution is:

the specific heat capasity for copper: 0:39 kJ / kg.C
and for water: 18.4 kJ / kg.C
dQ copper = m1 * CCU * (t1-t0) = 16.85 kJ

dQ water = m2* CH20 * (t0-t1) = 12:54 kJ

According to the first law of thermodynamics, the amount of heat transferred to the calorimeter and thermometer:

dQ = dQ copper - dQ water = 4.31 kJ

But how can I find the heat capacity of the calorimeter?
I see a solution that I should do this: 4.31 kJ / (26-20) C

but why water in this case?! should I always find the specific heat capacity of the calorimeter or the thermometer with respect to the minimum tempraturen?!
 
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Heat capacity(not specific heat) is nothing but mass times specific heat. If h be the heat capacity of the calorimeter including thermometer and your calculation is correct, then
##h(26-20) = 4.31##
 
Korak Biswas said:
Heat capacity(not specific heat) is nothing but mass times specific heat. If h be the heat capacity of the calorimeter including thermometer and your calculation is correct, then
##h(26-20) = 4.31##

Should I think:

Q los = Q gain

and Q gain = Q water + Q calorimeter ?!
 
Pouyan said:
Should I think:

Q los = Q gain

and Q gain = Q water + Q calorimeter ?!

Heat emitted by piece of copper = heat absorbed by water + heat absorbed by calorimeter including thermometer.
It follows from the conservation of energy.
 
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Korak Biswas said:
Heat emitted by piece of copper = heat absorbed by water + heat absorbed by calorimeter including thermometer.
It follows from the conservation of energy.
So we reduce 26 with the temprature of water for calorimeter ...is this always like this? If water is in the system should we find always the heat capacity of calorimeter with respect to water temprature ? What if water is not involved ?!I ask for an apology that I asked like this but I am a beginner...
thanks !
 
In a problem like this, it is assumed that the water and the calorimeter are initially in thermal equilibrium with each other before the copper is added. So, you can assume the calorimeter and the water have the same initial temperature (20 oC in this case.)

If there is no water so that the copper is placed in an empty calorimeter, then you would need to be given the initial temperature of the calorimeter.
 
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Pouyan said:
So we reduce 26 with the temprature of water for calorimeter ...is this always like this? If water is in the system should we find always the heat capacity of calorimeter with respect to water temprature ? What if water is not involved ?!I ask for an apology that I asked like this but I am a beginner...
thanks !
I think now you will have a clear idea after going through TSny's reply.
 
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