Thermochemistry relating delta H and q of surroundings

In summary, thermochemistry is the study of energy changes in chemical reactions and physical processes. Delta H and q of surroundings are two ways of measuring these changes, with delta H representing the change in enthalpy and q of surroundings representing the heat gained or lost by the surroundings. These values can be calculated using specific formulas and provide information about the direction and rate of a reaction. A negative delta H or q of surroundings indicates an exothermic reaction, while a positive value indicates an endothermic reaction. Additionally, these values can be used to predict the direction of a reaction, but other factors such as entropy must also be considered.
  • #1
garr6120
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Homework Statement


Why does ##\Delta H=\pm |q_{surroundings}|##?

Homework Equations

The Attempt at a Solution


Exothermic reactions have a ##-\Delta H## but does that mean that ##q## is a ##+q##. Vice versa for a endothermic reaction. I get confused on which sign i should use for which when i do my thermochemistry questions.
 
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  • #2
For an exothermic reaction at constant temperature and pressure, ΔH = q, and both are negative. For an endothermic reaction at constant temperature and pressure, ΔH = q, and both are positive.

Chet
 

1. What is thermochemistry and how is it related to delta H and q of surroundings?

Thermochemistry is the study of the energy changes that occur during chemical reactions and physical processes. Delta H and q of surroundings are two ways of measuring these energy changes, with delta H representing the change in enthalpy and q of surroundings representing the heat gained or lost by the surroundings.

2. How do you calculate delta H and q of surroundings?

Delta H can be calculated by subtracting the enthalpy of the products from the enthalpy of the reactants in a chemical reaction. Q of surroundings can be calculated using the formula q = m x c x delta T, where m is the mass of the surroundings, c is the specific heat capacity, and delta T is the change in temperature.

3. What is the significance of delta H and q of surroundings in a chemical reaction?

Delta H and q of surroundings provide information about the energy changes that occur during a chemical reaction. A negative delta H or a negative q of surroundings indicates an exothermic reaction, meaning energy is released to the surroundings. A positive delta H or a positive q of surroundings indicates an endothermic reaction, meaning energy is absorbed from the surroundings.

4. How does the magnitude of delta H and q of surroundings affect the rate of a reaction?

The magnitude of delta H and q of surroundings can affect the rate of a reaction. A higher energy release (negative delta H or q of surroundings) can increase the rate of an exothermic reaction, while a higher energy absorption (positive delta H or q of surroundings) can increase the rate of an endothermic reaction. This is because a higher energy change means more energy is available to fuel the reaction.

5. Can delta H and q of surroundings be used to predict the direction of a reaction?

Delta H and q of surroundings can provide information about the direction of a reaction. A negative delta H or q of surroundings indicates a spontaneous reaction, meaning it is likely to occur in the forward direction. A positive delta H or q of surroundings indicates a non-spontaneous reaction, meaning it is likely to occur in the reverse direction. However, other factors such as entropy must also be considered to accurately predict the direction of a reaction.

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