Thermodynamics: box with a moving wall

AI Thread Summary
The discussion centers on a thermodynamics problem involving a box with a movable wall separating two compartments of gas at different pressures. The main point of contention is the validity of equations used to determine the final pressure after the wall moves, particularly regarding whether the process is reversible or not. It is clarified that if the wall moves freely and is insulated, none of the provided answer options are correct, while if the wall moves gradually and is insulated, option C is correct with a necessary adjustment in the denominator. The final pressure can also be approximated under certain conditions, leading to a conclusion that if the wall is unconstrained, the final pressure would be 2P. The discussion concludes with a confirmation that these clarifications help in understanding the concept better.
Das apashanka
Moved from a technical forum, so homework template missing
I have a doubt regarding the answer, a box separated by a movable wall has two compartments filled by a monotonic gas .Initially the volumes are equal but the pressure are 3P and P respectively .When the wall is allowed to move the final pressure is
a.(2/3)γP
b.3(2/3)γP
C.(1+31/γ)γP/2
D.(31/γ/1+31/γ)γP
I have a doubt regarding option c as in the denominator I m getting 2ϒ
I want to clarify whether I m right
 
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I think you are right, I also obtain 2γ.
 
Please show your work.
 
3PVϒ=pV1ϒ
PVϒ=pV2ϒ
and V1+V2=2V
Where p=final state pressure and V1 and V2 are final state volume of the two boxes,V is the initial state volume
Solving the above three the result comes
 
The equations you are attempting to use are valid strictly to the case of an adiabatic reversible expansion and/or compression. If the wall is allowed to move with no constraint, the process will not be reversible, and the equations will not apply. Only if, during the process, the motion of the wall is controlled externally in very gradual increments will it be possible to carry out the process reversibly.

What is the exact statement of the problem?
 
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Chestermiller said:
The equations you are attempting to use are valid strictly to the case of an adiabatic reversible expansion and/or compression. If the wall is allowed to move with no constraint, the process will not be reversible, and the equations will not apply. Only if, during the process, the motion of the wall is controlled externally in very gradual increments will it be possible to carry out the process reversibly.

What is the exact statement of the problem?
the four options are given and only one is right,using the arguments given previous I obtained option c with an amendment I want to clarify whether I have done right and what will be the correct option
 
Das apashanka said:
the four options are given and only one is right,using the arguments given previous I obtained option c with an amendment I want to clarify whether I have done right and what will be the correct option
What is the EXACT statement of the problem?
 
Is the wall force to move gradually (so that the volume changes of the gases are reversible) or is it allowed to move freely (unconstrained)? Is the wall insulated (so that no heat can flow from one side to the other), or is it conductive of heat?
 
Chestermiller said:
Is the wall force to move gradually (so that the volume changes of the gases are reversible) or is it allowed to move freely (unconstrained)? Is the wall insulated (so that no heat can flow from one side to the other), or is it conductive of heat?
it is allowed to move freely and the wall is insulated
 
  • #10
Das apashanka said:
it is allowed to move freely and the wall is insulated
If this is the case, then none of the answers is correct.
 
  • #11
Chestermiller said:
If this is the case, then none of the answers is correct.
ok thank you
 
  • #12
Das apashanka said:
ok thank you
If the wall is forced to move gradually (not freely) and the wall is insulated, then the correct answer is C, if the 2 in the denominator is corrected to be ##2^{\gamma}##. If the wall is allowed to move freely and is not insulated, the final pressure is 2P.

It is also possible to approximate the solution to this problem if the wall is insulated and allowed to move freely if we assume that, on both sides of the wall, the pressure throughout the process is constant and equal to the final value of the pressure.
 
  • #13
Chestermiller said:
If the wall is forced to move gradually (not freely) and the wall is insulated, then the correct answer is C, if the 2 in the denominator is corrected to be ##2^{\gamma}##. If the wall is allowed to move freely and is not insulated, the final pressure is 2P.

It is also possible to approximate the solution to this problem if the wall is insulated and allowed to move freely if we assume that, on both sides of the wall, the pressure throughout the process is constant and equal to the final value of the pressure.
thanks it helps me in clearing the concept
 
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