Thermodynamics generic equation applications

In summary, the generic equation for thermodynamics is the First Law of Thermodynamics, which states that energy cannot be created or destroyed, only transferred or converted. This law is applied in real life in various systems such as car engines, cooking, and the human body. Common applications of thermodynamics equations include analyzing heat engines, gases, and refrigeration systems. Thermodynamics equations are also related to entropy, which is a measure of disorder in a system. The Second Law of Thermodynamics states that the entropy of a system will increase in any energy transfer or conversion. Finally, thermodynamics equations can be used to predict the direction of a chemical reaction through the Gibbs Free Energy equation, which takes into account the change in enthalpy and entropy.
  • #1
atmega-ist
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Homework Statement



I've been given a generic equation-->

A(aq) + 3B(aq) + C(s) --> 2D(aq) + X(g)

and am asked to fill in three columns witht the headings "Asked to find" with a list of variables; "Which equation(s) should you use?"; and "Show the equation using the general reaction where applicable".

The Attempt at a Solution



The first two are delta-H and dela-S both with the degree symbol and these are simple enough but the third asks for delta-H with no degree symbol ad at 50 degees C. I have delta-H = delta-E + delta-nRT for "which equation(s) should you use?"

My first question is: is this correct?

Secondly, the answer table implies that there's a way to show the equation with the general reaction. How in the world is this done?

I know there's a difference between the reactions at 25C and others but I can't seem to find it ANYWHERE in my book or study guide.

Thank you.
 
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  • #2


Thank you for your post. It seems like you have been given a challenging task and I am happy to assist you with it.

Firstly, your approach to using the equation delta-H = delta-E + delta-nRT for the variables delta-H and delta-S is correct. This equation relates the change in enthalpy (delta-H) to the change in internal energy (delta-E), the number of moles of gas (delta-n), and the temperature (T). However, please note that the equation for delta-S is slightly different and includes the factor of T as well, so it would be delta-S = delta-E + delta-nRln(T2/T1).

Secondly, to show the equation using the general reaction, you can simply replace the variables A, B, C, D, and X with the specific compounds or elements involved in the reaction. For example, the general reaction would look like this:

A(aq) + 3B(aq) + C(s) --> 2D(aq) + X(g)

But if you know the specific compounds involved, you can replace them in the equation, for example:

NaOH(aq) + 3HCl(aq) + 2H2O(l) --> 2NaCl(aq) + CO2(g)

I hope this helps clarify your doubts. If you have any other questions, please don't hesitate to ask. Good luck with your assignment!

 

1. What is the generic equation for thermodynamics?

The generic equation for thermodynamics is the First Law of Thermodynamics, also known as the Law of Conservation of Energy. It states that energy cannot be created or destroyed, only transferred or converted from one form to another.

2. How is the First Law of Thermodynamics applied in real life?

The First Law of Thermodynamics is applied in many real-life situations, such as the operation of a car engine, cooking food on a stove, or even the functioning of the human body. It helps us understand and predict how energy is transferred and converted in various systems.

3. What are some common applications of thermodynamics equations?

Some common applications of thermodynamics equations include analyzing the efficiency of heat engines, predicting the behavior of gases under different conditions, and understanding the principles behind refrigeration and air conditioning systems.

4. How do thermodynamics equations relate to entropy?

Entropy is a measure of the disorder or randomness in a system. The Second Law of Thermodynamics states that in any energy transfer or conversion, some energy will inevitably be lost as heat, and the overall entropy of the system will increase. Thermodynamics equations help us calculate the change in entropy in a system.

5. Can thermodynamics equations be used to predict the direction of a chemical reaction?

Yes, thermodynamics equations can be used to predict the direction of a chemical reaction. The Gibbs Free Energy equation takes into account the change in enthalpy and entropy of a reaction to determine whether it is spontaneous or non-spontaneous and in which direction it will proceed.

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