Thermodynamics/Statistical Mechanics Probability Questions

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SUMMARY

The discussion focuses on probability questions related to thermodynamics and statistical mechanics, specifically concerning ideal gases and molecular distributions. Key problems include calculating the probability of finding all molecules in a specific volume, determining the distribution of two types of molecules after a valve is opened, and assessing the probability of molecules in subdivided volumes. The equipartition theorem is mentioned but is deemed unnecessary for solving these probability problems, which can be approached through basic statistical reasoning.

PREREQUISITES
  • Understanding of ideal gas laws and properties
  • Familiarity with basic probability concepts
  • Knowledge of the equipartition theorem
  • Basic statistical mechanics principles
NEXT STEPS
  • Study the equipartition theorem in detail
  • Explore probability distributions in statistical mechanics
  • Learn about molecular dynamics simulations for ideal gases
  • Research applications of statistical mechanics in thermodynamic systems
USEFUL FOR

Students in physics or engineering disciplines, particularly those studying thermodynamics and statistical mechanics, as well as educators looking for problem-solving strategies in these areas.

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Homework Statement


On this problem set, there are multiple questions regarding the probability of events:

1. Consider a box of volume V containing N molecules. Assume that the molecules in the box are free of all interactions, that is, that the equation of state is that of an ideal gas.
(a) What is the probability of finding all the molecules in a portion of the container having a volume
V/2?
(b) If N=1023, what is the numerical value of this probability?

2. A volume V contains NA molecules of type A and NB molecules of type B. A valve is opened and M molecules flow out. What is the probability that among the M molecules there are mA of species A and mB of species B?

3. Suppose that a volume V is subdivided into M sub-volumes. Let there be N molecules in V. What is the probability that some one sub-volume will contain N’ molecules?

Homework Equations



Equipartition theorem

The Attempt at a Solution



I missed class, and I know the material I missed was the equipartition theorem. I am unsure if these problems require application of the equipartition theorem, or if I can just logic at them. Conveniently, this lecture was taken from a textbook that was not assigned for the course. Thoughts?
 
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I don't really think an understanding of equipartition theorem is required further than what Wikipedia can provide. Just consider it a big statistical problem (you have no interactions) and should be okay.
 
They don't. They're just probability problems.
 
Cool, thanks guys :)
 

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