Understanding Energy States and Population Distribution in Thermal Equilibrium"

In summary, the conversation discusses the calculation of temperature required to create a certain population distribution of energy states in thermal equilibrium. The formula for equating the number of electrons to the density of states and the Fermi distribution is mentioned. The given information can be used to solve for the temperature using the ratio of probabilities of the two states. The result obtained may be surprising.
  • #1
amph1bius
8
0
The Question

Consider two energy states, E2 = 2.0 eV and E1 = 1.0 eV. Assume that there are 1.0 x 10^16 electrons/cm^3 in E2 and 1.0 x 10^15 electrons/cm^3 in E1. What temperature is required to create this population distribution in thermal equilibrium?

How do you define the population distribution?

So far, I have a formula for equating number of electrons to the density of states * the fermi distribution.

How do I put the given information into a value for the "number of electrons"?

Thanks in advance
 
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  • #2
The probability of being in a given state is given by
$$
P(s) = \frac{e^{-E(s) / k T}}{Z}
$$
therefore one finds that the ratio of probabilities of the two states is
$$
\frac{P(2)}{P(1)} = \frac{e^{-E2 / k T}}{e^{-E1 / k T}}
$$
which one can then solve for ##T## using the given numbers.

Note: the result obtained in this particular case is quite surprising!
 

1. What are energy states?

Energy states refer to the different levels of energy that an atom or molecule can possess. These levels are determined by the arrangement and movement of the particles within the atom or molecule.

2. How are energy states related to the behavior of matter?

The behavior of matter is directly influenced by the energy states of its particles. The higher the energy state, the more energy the particles have, and the more active and dynamic they become.

3. What factors affect the energy states of particles?

The energy states of particles can be affected by various factors such as temperature, pressure, and interactions with other particles. Changes in these factors can cause the particles to move to a higher or lower energy state.

4. How do energy states change during chemical reactions?

In a chemical reaction, energy is either released or absorbed as the particles rearrange themselves. This energy change can cause the particles to move to a different energy state, depending on the new arrangement of the particles.

5. What is the significance of energy states in understanding matter?

Studying energy states allows us to understand the behavior and properties of matter. It helps us explain how and why matter undergoes physical and chemical changes, and how these changes affect our daily lives.

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