An organic functional group is a specific grouping of atoms within a molecule that determines its chemical reactivity and properties. These groups, such as hydroxyl, halogens, carboxylic acids, amines, and sulfhydryl, can significantly influence the pH of a solution. This occurs because certain functional groups can either dissociate a proton (H+) or accept a proton, thereby affecting acidity or basicity. Carboxylic acids are highlighted as a key example due to their ability to release protons, lowering pH. For further study, organic chemistry textbooks like "Organic Chemistry" by Wade and "McMurry" provide comprehensive information on functional groups and their implications.