Understanding the Law of Multiple Proportions

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The Law of Multiple Proportions states that when two elements form multiple compounds, the masses of one element that combine with a fixed mass of the other are in ratios of small whole numbers. This implies that atoms combine in whole numbers, meaning fractional atoms do not participate in bonding. The discussion highlights the complexity of expressing these ratios, using Fe2O3 as an example where the Fe to O ratio is 2:3, despite initial appearances suggesting a 1:1.5 ratio. Understanding these principles is crucial for grasping chemical combinations and stoichiometry. The conversation reinforces the importance of whole number ratios in chemical compounds.
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Law of multiple proportions states that "if two elements can combine to form more than one compound, the masses of one element that combine with a fixed mass of the other element, are in the ratio of small whole numbers"
I was thinking how it makes sense. and i concluded this just simply means that atoms can only combine in whole no.s i.e 1/2 of a atom does not combine...1,2,3 atoms will.
am i thinking right?


 
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I think you're right. Sometimes the ratios are a little tricky. How about Fe2O3? Ratio of Fe to O is 1:1.5 but should be expressed as 2:3.
 
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