Unveiling the Mystery: How is the Wavefunction of an Electron Revealed?

In summary, the wave function of an electron is determined by solving Schrodinger's equation, and the sine wave (and sums of sine waves) are the solution for a free particle such as an electron in empty space. This technique is used in fields such as electronic structure theory, theoretical condensed matter physics, and quantum chemistry. Recently, a technique has been developed to generate an actual picture of the wave function for several electron orbitals of a hydrogen atom, which has been featured in popular reporting. However, there is a distinction between an "actual picture of the wave function" and a "picture of the actual wave function."
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  • #2
The wave functions are the solutions of Schrodinger's equation; if you want to know what the wave function "looks like" you have to set up and solve that equation. The sine wave (and sums of sine waves) are the solution for a free particle such as an electron hanging out in empty space.
 
  • #3
Thank you. That helped alot
 
  • #4
On a related note, doing precisely this, calculating electronic wave functions (or similar quantities) of realistic physical systems like molecules and solids is the main subject of a a large branch of physics called "electronic structure theory". Techniques to do this are dealt with in theoretical condensed matter physics and quantum chemistry.
 
  • #6
PhilDSP said:
There is a recently developed technique which generates an actual picture of the wave function for several electron orbitals of a hydrogen atom using composite snapshots:

http://physics.aps.org/featured-article-pdf/10.1103/PhysRevLett.110.213001

Popular reporting:
http://www.foxnews.com/science/2013/05/28/amazing-first-ever-photograph-inside-hydrogen-atom/

And the comparison between the two should be enough to turn you off from popular reporting forever... No :smile: here.

Note that an "actual picture of the wave function" is not the same thing as a "picture of the actual wave function". This isn't a criticism, as the work in question is still quite fascinatingly cool.
 

Related to Unveiling the Mystery: How is the Wavefunction of an Electron Revealed?

1. What is the wavefunction of an electron?

The wavefunction of an electron is a mathematical function that describes the probability of finding an electron in a particular location in space. It is represented by the Greek letter psi (ψ) and is a fundamental concept in quantum mechanics.

2. How is the wavefunction of an electron related to its energy?

The wavefunction of an electron is related to its energy through the Schrödinger equation, which describes how the wavefunction changes over time. The energy of an electron is determined by the shape of its wavefunction and the potential energy of its surroundings.

3. Can the wavefunction of an electron be observed directly?

No, the wavefunction of an electron cannot be observed directly. It is a mathematical concept that describes the probability of finding an electron in a particular location, rather than a physical object that can be observed.

4. How does the wavefunction of an electron change in different environments?

The wavefunction of an electron can change in different environments due to the influence of external factors, such as electric and magnetic fields. These factors can alter the shape and energy of the wavefunction, affecting the behavior of the electron.

5. Why is the wavefunction of an electron important in quantum mechanics?

The wavefunction of an electron is important in quantum mechanics because it is used to calculate the behavior and properties of electrons and other particles at the atomic and subatomic level. It allows scientists to make predictions and understand the behavior of particles in a quantum system.

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