Understanding Equipartition & Statistical Mechanics: Part a & b

In summary, for part a, Cv = R for a monoatomic ideal gas confined in two dimensions and for part b, Cv = NR for a system of N independent harmonic oscillators in two dimensions.
  • #1
A.Brown
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Homework Statement


Part a: A monoatomic ideal gas is confined to move in two dimensions. What is Cv for this gas?

Part b: Consider a system composed of N independent harmonic oscillators in two dimensions. What is Cv for the system?

Homework Equations


Cv = ∂U/∂T
U = (number of degrees of freedom)(1/2 NAkBT = (number of degrees of freedom)(1/2)RT

The Attempt at a Solution



I'm not very confident about this:

Part a: Since the gas is monatomic, it only has translational degrees of freedom, and it is given that these are restricted to two.

(2)(1/2)RT = RT and Cv = R

Part b: Since it's a harmonic oscillator, there's a degree of freedom for U and K for each dimension, so 4 degrees of freedom, and Cv = 2R? I'm not sure what to do with the N though, since it's an average, it shouldn't affect the Cv? Or am I misunderstanding?
 
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  • #2


For part a, your answer is correct. Since the gas is confined to move in two dimensions and it is monatomic, it only has two translational degrees of freedom. Therefore, Cv = R.

For part b, you are correct that each harmonic oscillator has two degrees of freedom (for U and K in each dimension), so for N oscillators, there are 2N degrees of freedom. Therefore, Cv = (2N)(1/2)R = NR. The N does not affect the Cv as it is a constant and does not change with temperature.
 

1. What is equipartition theorem?

The equipartition theorem states that in thermal equilibrium, the total energy of a system is evenly distributed among all degrees of freedom, where each degree of freedom contributes an average energy of 1/2kT, where k is the Boltzmann constant and T is the temperature in Kelvin.

2. How does the equipartition theorem relate to statistical mechanics?

The equipartition theorem is a fundamental concept in statistical mechanics, which is the study of the behavior of large systems of particles. It helps to explain the relationship between energy, temperature, and the degrees of freedom of a system.

3. What are the assumptions of the equipartition theorem?

The equipartition theorem is based on the following assumptions: 1) the system is in thermal equilibrium, 2) the particles in the system are non-interacting, 3) the potential energy of the system is quadratic, and 4) the energy levels of the system are evenly spaced.

4. What are the limitations of the equipartition theorem?

The equipartition theorem is only valid for systems in thermal equilibrium and with non-interacting particles. It also does not apply to systems with non-quadratic potential energy or with energy levels that are not evenly spaced. In addition, it does not take into account quantum effects, which become significant at low temperatures.

5. How is the equipartition theorem used in practical applications?

The equipartition theorem is used in a variety of practical applications, including thermodynamics, chemistry, and materials science. It is also used in the design of mechanical systems and in the calculation of heat capacities. Additionally, it is a key concept in understanding the behavior of gases and the properties of materials at the atomic and molecular level.

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