What Does the First Law of Thermodynamics Really Imply?

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The First Law of Thermodynamics states that energy cannot be created or destroyed, only transformed, which raises questions about work done by a system. A common misconception is that a system can only perform external work if its internal energy decreases, which is incorrect. Additionally, to accurately calculate temperature, one must consider the thermal energy difference between two bodies, not just the amount of thermal energy contained. At standard temperature and pressure (STP), the temperature is 273.15 K, and the pressure is 1 atm, equivalent to 101325 Pa. Understanding these principles is crucial for applying thermodynamic concepts correctly.
jack1234
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1.
One question ask
"Which statement below regarding the First Law of Thermodynamics is best? Select the correct answer."
One of the wrong answer is
"A system can do work externally only if its internal energy decreases. "
What does it mean do work externally?

2.
Another question ask
"Which of the following statements is true? Select the correct answer."
One of the wrong answer is
"You only need to know the amount of thermal energy a body contains to calculate its temperature. "
How to correct this sentence?

3.
For definition STP,
the tempature is 273.15k,
but what is the pressure in the unit of pa and atm?
 
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jack1234 said:
1.
One question ask
"Which statement below regarding the First Law of Thermodynamics is best? Select the correct answer."
One of the wrong answer is
"A system can do work externally only if its internal energy decreases. "
What does it mean do work externally?

If you have a gas in a cylinder with a piston, and you compress that gas wit the piston, you are doing work on the gas.

If you attempt to hold that piston down and ignite the gas (assume it's a mixture of air a fuel), then the gas is doing work on the piston (externally).

If the gas, despite being ignited, is not able to push the piston up, then all the work done is actually 0, yet the energy has to go somewhere. The energy remains in the gas as heat. The work done by the gas is internal and it heated up.

2.
Another question ask
"Which of the following statements is true? Select the correct answer."
One of the wrong answer is
"You only need to know the amount of thermal energy a body contains to calculate its temperature. "
How to correct this sentence?

What are the other answers?

3.
For definition STP,
the tempature is 273.15k,
but what is the pressure in the unit of pa and atm?

1 atm = 101325 Pa.
 
Thanks,
What are the other answers?
a. is correct, other is wrong

a.The quantity of thermal energy exchanged by two bodies in contact is directly proportional to the difference in their temperatures.
b.You only need to know the amount of thermal energy a body contains to calculate its temperature.
c.The temperature of a body is directly proportional to the amount of work the body has performed.
d.The quantity of thermal energy exchanged by two bodies in contact is inversely proportional to the difference in their temperatures.
e.Different amounts of thermal energy are transferred between two bodies in contact if different temperature scales are used to measure the temperature difference between the bodies.
 
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