What is the final volume of the container?

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Homework Help Overview

The problem involves a container with a piston, initially filled with a substance, and heated over a specified time. The goal is to determine the final volume of the container after heating, given initial conditions such as volume, pressure, and temperature.

Discussion Character

  • Exploratory, Assumption checking, Conceptual clarification

Approaches and Questions Raised

  • Participants discuss the application of the ideal gas law and the relevance of specific heat capacities for different substances. There is an exploration of whether the container is filled with water or a gas, which affects the approach to the problem.

Discussion Status

Participants are actively questioning assumptions about the nature of the substance in the container and the appropriateness of the equations used. Some have provided alternative perspectives on the physical principles involved, while others are verifying calculations and unit consistency.

Contextual Notes

There is a noted confusion regarding the substance in the container, with initial references to water later corrected to a monatomic gas. This has implications for the specific heat capacity used in calculations.

houseguest
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Homework Statement


A container has a 100 cm^2 piston with a mass of 10 kg that can slide up and down vertically without friction and is placed below a heater.
Suppose the heater has 25 W of power and are turned on for 15 s. What is the final volume of the container?

Initial Volume: 800 cm^{3}
Initial Pressure: 1.11*10^{5} Pa
Initial Temperature: 20 C

Homework Equations



pV = nRT
Q = p_{power}\Deltat = nC_{p}\DeltaT

The Attempt at a Solution



Using pV = nRT and knowing that p_i = p_f I can get V_{f} = V_{i}T_{f} / T_{i}

I now need T_{f}

To get that I used
p_{power}\Deltat = nC_{p}\DeltaT

to get

T_{f}] = p_{power}\Deltat/nC_{p}] + T]_{i}

Then I used p_{i}V_{i} = nRT_{i} to replace n and I got (after much simplifying)

V_{f} = p_{power}*\Deltat*R/[ p_{i}C_{p} ] + 1

I then plugged in all the numbers (using C_{p} of water = 4100 and got:

25*15*8.314/(1.11*10^5*4100) + 1 = 1.00000685 m^3

Which gives \approx 1.000006.85 * 10^6 cm^3

I have a very hard time believing that is the answer -- it's just too large.

Any help pointing out the stupid thing(s) I did would be very appreciated!

THANKS!
 
Last edited:
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Hi houseguest,

Did you type in the entire question? You used C_p of water in part of your solution, but I don't see where water appears in the problem.
 
Sorry, I forgot to mention that the container is filled with water.
 
I hope I'm not misunderstanding the problem. However one point is that if the container volume is increasing because it's filled with water and the water volume is increasing, then you cannot use PV=nRT. (That applies to ideal gases.) Instead use the formula for volume expansion of a solid or liquid.
 
Wow! I'm sorry, that was definitely one of my stupid things. Thanks for pointing that out! The container is filled with a monatomic gas. So I should be using C_p for that.
So, since C_p = R + C_v and C_v = 3/2 * R ( for a monatomic gas) then C_p = 5/2 * R

So that would give ( with the R's canceling)

25*15/(1.11*10^5 * 5/2) + 1 = 1.00135 m^3 = 1.00135 * 10^6 cm^3

However, this (I would think) is still too large. Any ideas?

Thanks for your help!
 
I see at least one error involving R. Try carrying your units along with each term to make sure everything cancels out OK.
 

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