What is the Standard Reduction Potential for 2CO2 + 2e- <-> (C2O4)^2-?

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Discussion Overview

The discussion centers around the standard reduction potential for the semireaction involving carbon dioxide and oxalate ion, specifically the reaction 2CO2 + 2e- <-> (C2O4)^2-. Participants seek to identify or calculate this potential, exploring various sources and methods.

Discussion Character

  • Exploratory, Technical explanation, Debate/contested

Main Points Raised

  • One participant requests assistance in finding the standard reduction potential for the specified semireaction.
  • Another participant suggests calculating the potential from the Gibbs energies of formation for carbon dioxide and oxalate, referencing a specific online resource.
  • A different participant cites Inczédy, stating that the standard reduction potential is -0.64 V, referencing W.M. Latimer's Oxidation potentials as a source.
  • A repeated request for the same standard reduction potential includes an alternative reaction involving H2C24 with an electrode potential of -0.49 V.

Areas of Agreement / Disagreement

Participants do not appear to reach a consensus on the standard reduction potential, as multiple values and methods are proposed without agreement on a definitive answer.

Contextual Notes

There are references to different sources and methods for calculating or identifying the standard reduction potential, indicating potential variability in values depending on the approach taken.

Who May Find This Useful

This discussion may be of interest to those studying electrochemistry, particularly in the context of standard reduction potentials and their calculations.

Ann Par
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Good afternoon, i have been trying to find without success the standard reduction potential for the next semireaction:

2CO2 +2e- <-> (C2O4)^2-
Could someone please help me with that or tell me where could i find this potencial?. Thanks
 
Chemistry news on Phys.org
Inczédy lists it as -0.64 V, giving W.M. Latimer's Oxidation potentials as a source.
 
Ann Par said:
Good afternoon, i have been trying to find without success the standard reduction potential for the next semireaction:

2CO2 +2e- <-> (C2O4)^2-
Could someone please help me with that or tell me where could i find this potencial?. Thanks
2CO2 + 2H+ + 2e- = H2C24 (electrode potential is -0.49V)
 

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