Discussion Overview
The discussion centers around the standard reduction potential for the semireaction involving carbon dioxide and oxalate ion, specifically the reaction 2CO2 + 2e- <-> (C2O4)^2-. Participants seek to identify or calculate this potential, exploring various sources and methods.
Discussion Character
- Exploratory, Technical explanation, Debate/contested
Main Points Raised
- One participant requests assistance in finding the standard reduction potential for the specified semireaction.
- Another participant suggests calculating the potential from the Gibbs energies of formation for carbon dioxide and oxalate, referencing a specific online resource.
- A different participant cites Inczédy, stating that the standard reduction potential is -0.64 V, referencing W.M. Latimer's Oxidation potentials as a source.
- A repeated request for the same standard reduction potential includes an alternative reaction involving H2C24 with an electrode potential of -0.49 V.
Areas of Agreement / Disagreement
Participants do not appear to reach a consensus on the standard reduction potential, as multiple values and methods are proposed without agreement on a definitive answer.
Contextual Notes
There are references to different sources and methods for calculating or identifying the standard reduction potential, indicating potential variability in values depending on the approach taken.
Who May Find This Useful
This discussion may be of interest to those studying electrochemistry, particularly in the context of standard reduction potentials and their calculations.