The current center of mass energy is 13 TeV, by the way.
As protons are not elementary particles, the collisions are better described by collisions of "parts" of the protons, those "parts" are called partons. They have some fraction of the total energy of the protons, and more than half of the proton energy is extremely rare. Therefore, we can search for more high-energetic particles, but not up to 13 TeV. The actual sensitivity depends on the specific model considered ("how likely is the production of particle X in model Y?"), but for every model increasing the energy helps to search for heavier particles.