PV equals zero for solids because, in a solid state, the volume remains constant under pressure, leading to no work done (W = PΔV). Pressure (P) in solids is often considered in terms of stress rather than a direct measure like in fluids. While solids can exert pressure, they do not possess pressure in the same way fluids do, as they do not flow or change volume easily. The discussion highlights the need to clarify the definitions of pressure and volume in the context of solid mechanics. Understanding these concepts is crucial for accurately interpreting the behavior of solids under stress.