Work done by product gas in reversible adiabatic expansion

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Calculating the work done by a product gas during reversible adiabatic expansion involves using the equations pV^γ = constant and integrating the work done as W = ∫P.dV. The discussion highlights the need for initial parameters, including initial volume, temperature, and the number of moles of gas, to determine the initial pressure using the ideal gas law. The user is working with a combustion reaction of ethanol, with a volume change from 0.02 m³ to 0.04 m³ and an initial temperature of 4000 K. Participants suggest substituting equations and integrating to find a relationship between volume and temperature. Understanding these relationships is crucial for accurately calculating the work done and final temperature in the expansion process.
Egbert
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I am having trouble calculating the work done by a product gas in reversible adiabatic expansion, and in calculating the final temperature. pV gamma = constant, Cv = constant (assume), gamma = cv + nR / Cv.
anyone who can help me out?
 
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Work done = ∫P.dV
PVγ = P1V1γ = P2V2γ

Try substituting one equation in the other and integrating from V1 to V2
 
I only know the V1, V2 and n. Should this work or should I assume a P1 of 1 bar?
 
What parameters do you know about the gas in its initial state before the expansion?

Chet
 
I
Chestermiller said:
What parameters do you know about the gas in its initial state before the expansion?

Chet
t is a combustion reaction of ethanol, volume is increasing from 0.02 m3 to 0.04 m3 with a starting temperature of 4000 K. Also the amounts are known. (12g ethane and enough oxygen)
Thanks
 
Egbert said:
I

t is a combustion reaction of ethanol, volume is increasing from 0.02 m3 to 0.04 m3 with a starting temperature of 4000 K. Also the amounts are known. (12g ethane and enough oxygen)
Thanks
You know the initial volume, the initial number of moles of gas, and the initial temperature. From the ideal gas law, what do you get for the initial pressure?

Chet
 
Using PV = nRT and PVγ = constant, can you devise an equation with 'V' and 'T'?
 
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