Q-spacing, Bragg-spacing, D-spacing & Repeat Distances Explained

In summary, Q-spacing is the length of a reciprocal lattice vector, while d-spacing is the interplanar distance in a crystal. The Bragg-spacing is any distance over which a system is translationally invariant and can produce a Bragg peak. The relationship between reciprocal and real lattice vectors varies depending on the type of Bravais lattice.
  • #1
thearny
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Could anyone tell me what the difference between Q-spacing Bragg-spacing D-spacing and repeat distance is? I've always thought that they were same, but seemingly not? What is the realtionship, what is Q?

Its keeping me up at night!
 
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  • #2
d-spacing is simply the interplanar distance in a crystal. In this context, the Q-spacing is the length of a reciprocal lattice vector (you have a Bragg peak when the wave vector of the radiation used matches a reciprocal lattice vector). The Bragg-spacing is any distance over which a system is translationally invariant in some direction, and will hence produce a Bragg peak. So, in a crystal, the bragg spacing will be the d-spacing itself. In an superalloy, you will see an adiitional larger (but weaker) Bragg peak giving rise to an additional Bragg spacing. Likewise, you can have a Bragg spacing for a polymer and even a liquid crystal.

The relationship between reciprocal lattice vectors and real lattice vectors depends on the type of Bravais lattice involved.
 
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  • #3


Q-spacing, Bragg-spacing, D-spacing, and repeat distance are all related concepts used in crystallography to describe the periodicity of a crystal lattice. While they may seem similar, they actually have distinct definitions and uses.

Q-spacing refers to the distance between two Bragg peaks in a diffraction pattern. This distance is measured along the direction of the incident X-rays and is used to calculate the spacing between planes of atoms in the crystal lattice.

Bragg-spacing, on the other hand, refers to the distance between two adjacent crystal planes in the lattice. This distance is measured in the actual crystal structure and is related to the Q-spacing by a mathematical equation.

D-spacing, also known as interplanar spacing, is the distance between two parallel crystal planes in the lattice. It is directly related to the Bragg-spacing and is used in diffraction experiments to determine the crystal structure of a material.

Repeat distance, sometimes called lattice spacing, is the distance between identical points on adjacent unit cells in a crystal lattice. It is related to the D-spacing and is used to describe the periodicity of the crystal lattice.

In summary, Q-spacing, Bragg-spacing, D-spacing, and repeat distance are all related to each other, but they have distinct definitions and uses in crystallography. Q-spacing is used in diffraction experiments, while Bragg-spacing, D-spacing, and repeat distance are used to describe the crystal lattice itself. Q refers to the scattering vector in diffraction experiments and is related to the other spacing parameters through mathematical equations.
 

1. What is the difference between Q-spacing, Bragg-spacing, and D-spacing?

Q-spacing, Bragg-spacing, and D-spacing are all related to the spacing between atoms in a crystal lattice. Q-spacing, also known as reciprocal lattice spacing, refers to the distance between two adjacent lattice points in the reciprocal lattice. Bragg-spacing, named after physicist William Lawrence Bragg, is the distance between two crystal planes that satisfy the Bragg diffraction condition. D-spacing, or interplanar spacing, is the distance between two parallel crystal planes.

2. How are Q-spacing and Bragg-spacing related?

Q-spacing and Bragg-spacing are inversely related, meaning that as one increases, the other decreases. This is because the Bragg diffraction condition is satisfied when the path difference between two diffracted rays is equal to an integer multiple of the wavelength. Since the wavelength is constant, this means that as the distance between planes (Bragg-spacing) increases, the angle of diffraction decreases and the reciprocal lattice spacing (Q-spacing) increases.

3. How is D-spacing calculated?

D-spacing is calculated using Bragg's law: nλ = 2d sinθ, where n is the order of diffraction, λ is the wavelength of the incident X-ray, d is the interplanar spacing, and θ is the angle of diffraction. Rearranging this equation gives d = nλ/2sinθ. This means that the interplanar spacing is directly proportional to the wavelength and inversely proportional to the sine of the diffraction angle.

4. What is the significance of repeat distances in crystallography?

Repeat distances, also known as lattice parameters, are important in crystallography because they describe the size and shape of the unit cell in a crystal lattice. These parameters determine the arrangement of atoms within the crystal and can provide valuable information about the crystal's physical and chemical properties.

5. How are repeat distances measured?

Repeat distances can be measured using a variety of techniques, including X-ray diffraction, electron diffraction, and neutron diffraction. These methods involve bombarding the crystal with a beam of particles or radiation and analyzing the resulting diffraction pattern. From this pattern, the repeat distances can be calculated using mathematical formulas such as Bragg's law.

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