Stability of Highest Oxidation State

AI Thread Summary
The stability of the highest oxidation state decreases from group 13 to group 17 due to the increasing energy difference between ns and np orbitals as atomic number rises. This increase in energy difference is attributed to the greater effective nuclear charge, which enhances the nucleus's attraction to electrons. As a result, the ability of elements to maintain higher oxidation states diminishes. The discussion emphasizes the relationship between orbital energy levels and electron affinity in understanding this trend. Overall, the stability of oxidation states is closely linked to atomic structure and electron interactions.
ritwik06
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Homework Statement



Why does the stability of highest oxiation state decreases from group 13 to group 17?

Ans: My book says, that with the increase in atomic number, difference in energies between ns and np orbitals increases. Is it right? If so then can u please explain what relation exists between the statements.
 
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It's better to consider this in terms of electron affinity. The energies between ns and np orbitals increases because of the increase in effective nuclear charge i.e. " it wants the electrons more " .
 
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