Steam condensation in the presence of air

AI Thread Summary
When steam condenses on a cold surface in the presence of air, the increased concentration of air at the condensation interface lowers the steam pressure and temperature due to the partial pressure effect. This phenomenon occurs because the presence of non-condensables like air reduces the effective driving force for condensation, leading to a lower steam pressure rather than an overall increase in system pressure. The heat transfer coefficient and heat transfer rate decrease with higher non-condensable concentrations, as the steam temperature drops. Although a decrease in steam temperature suggests reduced thermal resistance, the overall heat transfer is compromised due to the presence of non-condensables. Understanding these dynamics is crucial for optimizing condenser performance in systems with air or other non-condensable gases.
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I've been reading about this topic in a book recently and it states that when steam (water vapor) condenses on a cold surface in the presence of air, the increase in air concentration at the condensation interface causes a reduction in the steam pressure and hence, temperature. I am wondering why this is the case? Why does the overall system pressure not just increase? For example, in a condenser operating with non-condensables (such as air), I understand that the partial pressure of air will increase at the condensation interface due to the increase in concentration there but would that increase in partial pressure not just increase the overall condenser pressure instead of depressing the steam pressure & temperature?

Please feel free to show me the error of my ways.
 
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Care to share a reference to what you've been reading?
 
Its in a book called "Liquid-Vapor Phase Change Phenomena" by Van P. Carey.

I have also read some papers which show that both the condensation heat transfer coefficient and heat transfer decrease as non-condensable concentration increases. It makes sense that if the steam temperature decreses due to the presence of air (non-condensable gas), then the heat transfer rate must accordingly decrease. However, if the steam temperature decreases, it implies that the thermal resistance to heat flow decreases and the heat transfer coefficient must then be increasing.

Any ideas?
 
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