What is your definition of thermodynamic equilibrium as it applies to pure radiation?
[PLAIN said:
http://www.grc.nasa.gov/WWW/K-12/airplane/thermo0.html]The[/PLAIN] zeroth law of thermodynamics begins with a simple definition of thermodynamic equilibrium . It is observed that some property of an object, like the pressure in a volume of gas, the length of a metal rod, or the electrical conductivity of a wire, can change when the object is heated or cooled. If two of these objects are brought into physical contact there is initially a change in the property of both objects. But, eventually, the change in property stops and the objects are said to be in thermal, or thermodynamic, equilibrium. Thermodynamic equilibrium leads to the large scale definition of temperature.
The above definition I think applies equally well to radiation as to matter. The only
possible difference is that if you took two fields of radiation, say the CMB and the thermal radiation from a neutron star, and put them in a region of space, they
might never interact at the level that they can acquire the same "property" (temperature). The reason I say it's only a possible difference is that I don't think it's known whether photons can interact at the level required to reach equilibrium. If so, it would take a finite (though admittedly enormous) amount of time for them achieve the same "property" and they would satisfy the definition entirely. Even if this is not the case, then one could still make the argument that the photons are not in "physical contact", and are therefore not violating the definition.
However, there is no question that when put into thermal contact with matter in a closed system, the photons will reach equilibrium with the matter. To me, it makes the most sense to think of temperature in terms of statistical equilibrium and, regardless of whether or not the photons do interact with one another, I would say they can have a temperature.
Andrew Mason said:
Two gases with different specific heats will have two different temperatures when placed in the same blackbody radiation field.
Not once they've reached equilibrium. The specific heat tells you how much energy is required to change the temperature of an object (per unit mass), it does not tell you about the final equilibrium temperature in such a situation. In the example of shining a laser on an object for a certain amount of time, the final result
would depend on the specific heat because you're giving it a set amount of energy. In the case of embedding a body in a blackbody radiation field, if given enough time, it can take any amount of energy it needs to reach equilibrium with the radiation. When the input energy per unit time is equal to the output energy per unit time, the body is in eqilibrium and will no longer change its temperature. The time it takes for this to occur will depend on the specific heat, but the final temperature will not.
The laser source will reach a stable temperature and emit a blackbody spectrum typical of that temperature. It will also emit a swack of identical photons whose frequency depends on the energy level of the excited electrons in the laser material. If blackbody radiation has a temperature, why don't the laser photons?
Lasers require non-equilibrium conditions to be created. In an atomic gas, the atoms are not in complete equilibrium unless the distribution of their energy levels is given by the ratios of the Boltzmann factors (see http://www.chemsoc.org/exemplarchem/entries/pkirby/exemchem/Boltzmann/Boltzmann.html , for example). If the energy levels of the source atoms satisfied this criterion, stimulated emission could not occur and there could be no population inversion. Thus, if you put the laser and its target in a closed system (this is crucial for equilbrium to occur), the source of the laser emission would eventually reach an equilibrium population of energy levels and, at this point, would begin to emit a blackbody spectrum rather than a monochromatic beam.
As Chronos points out, the definition of temperature is somewhat elusive.
Yes, I will certainly concede that point. Like I said earlier, I think we'll just have to agree to disagree, since the physics community doesn't seem to be in agreement about the definition either.