Analytical Chemistry UF: Comparing Wavelengths & Frequencies

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Discussion Overview

The discussion revolves around a question from an Analytical Chemistry final exam regarding the relationship between the wavelengths and frequencies of the sodium D1 line in vacuum and air. Participants explore the implications of changes in wavelength due to the medium and the constancy of frequency.

Discussion Character

  • Homework-related

Main Points Raised

  • One participant suggests that the difference in wavelengths is due to the change in the speed of light in different media and questions whether the frequency remains constant for both wavelengths.
  • Another participant asserts that the difference in frequency is zero.
  • Some participants performed calculations and arrived at a frequency difference of 1.409x10^11 Hz.

Areas of Agreement / Disagreement

There is disagreement regarding the correct interpretation of the frequency difference, with some participants claiming it is zero while others provide a calculated frequency difference.

Contextual Notes

Participants have not resolved the assumptions regarding the constancy of frequency across different media and the implications of the speed of light in vacuum versus air.

WhoYaWitt
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Question 20 from our final I just took (Analytical Chemistry UF).

"You may recall that the wavelength of the sodium D1 line in vacuum is 589.7558nm. In air it becomes 589.5924nm. What is the difference in frequency for these two wavelengths."


I said 0. All the other people did the math for the two wavelengths and subtracted them and got 1.409x10^11 Hz.

The test was multiple choice so they were both potential responses.

Am I right in assuming that the difference in their wavelengths was due to the change in speed of light in a vacuum vs air? And that the frequency is supposed to be constant for both? Or is this not the same thing?

Thx!
 
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Zero is the correct answer.
 


Sweet that gives me a 95 on the final and I needed a 93 to get the A :biggrin:
 


(and thanks for the reply as well)
 

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