Calculating Total Entropy Change for a Three-Step Process

AI Thread Summary
The discussion revolves around calculating the total entropy change for a three-step process involving an ideal gas. The first step is an isothermal expansion at 300K, contributing 34.6 J/K to the entropy change. The second step is an adiabatic expansion, resulting in zero entropy change. For the third step, which is neither adiabatic nor isothermal, the entropy change is calculated as -34.6 J/K, balancing the total entropy change to zero for the cyclic process. Concerns are raised about whether all provided information is utilized effectively in the calculations.
StonieJ
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Question:
Three moles of an ideal gas (CV,m = 7/2R) initially at 300K are taken through a series of three compression/expansion steps:

The gas is expanded isothermally and reversibly at 300K. This process involves 10.37 kJ of heat going into the system.
The gas is then expanded reversibly and adiabatically to a new volume and temperature. This process involves no heat.
The gas is then compressed in a process that is neither adiabatic nor isothermal until it is back to the original state where it started. This process involves an unknown amount of heat, but we do know that for this process ?Ssurroundings = 40 J/K.
What is dStotal for process 3?



I tried solving this by simply saying that the sum of dS for steps 1, 2, and 3 were zero, since the process is cyclic. Therefore:

dS1 + dS2 = -dS3

We are told the reversible heat for step 1, so we can find it by:

dS1 = qrev/T = 10.37 kJ / 300 K = 34.6 J/K

The second step is adiabatic, so q = 0, and therefore dS2 = 0. This results in:

dS3 = -dS1 = -34.6 J/K.

My biggest concern is that I'm not using enough information provided by the question.
 
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you seem to be doing fine,
 
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