Carnot efficiency: is heat always positive?

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Discussion Overview

The discussion revolves around the interpretation of heat quantities in the Carnot efficiency equation, specifically whether both heat quantities (Q_H and Q_C) should be treated as positive values despite their directional flow in the context of a heat engine. The scope includes theoretical understanding and clarification of the efficiency equation.

Discussion Character

  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • Some participants assert that both Q_H and Q_C can be treated as positive in the efficiency equation e=1-Q_C/Q_H, with the minus sign accounting for the direction of heat flow.
  • One participant emphasizes that Q_H is the heat input into the system and Q_C is the heat expelled, suggesting both should be treated as positive quantities to avoid confusion in calculations.
  • Another participant clarifies that efficiency measures the work done relative to the heat supplied, indicating that the focus should be on the ratio of work to heat input rather than a direct comparison of heat lost to heat gained.
  • There is a mention of the first law of thermodynamics and its relation to the efficiency equation, with references to the internal energy change and work done by the gas.
  • Some participants express confusion regarding the treatment of heat quantities and the implications for the efficiency calculation, particularly in relation to the sign convention used.

Areas of Agreement / Disagreement

Participants express differing views on how to treat the heat quantities in the efficiency equation, with no consensus reached on whether both should be considered positive or if the sign convention adequately reflects their roles in the equation.

Contextual Notes

There are unresolved questions regarding the implications of sign conventions on the efficiency calculation and the interpretation of heat flow in the context of thermodynamic cycles.

danrochester
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This is a very quick question but in the equation

[tex]e=1-Q_{C}/Q_{H}[/tex]

do we treat both Q's as positive even though heat goes in in one case and out in the other? Or is there some detail I'm missing that would otherwise make the result less than 1.
 
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The answer is yes. The minus sign takes into account the difference you stated above.
 
danrochester said:
This is a very quick question but in the equation

[tex]e=1-Q_{C}/Q_{H}[/tex]

do we treat both Q's as positive even though heat goes in in one case and out in the other? Or is there some detail I'm missing that would otherwise make the result less than 1.
Giordanus is correct. Heat flow is measured relative to the engine (gas): Qh is into the gas - positive - and Qc is out of the gas - negative. The equation derives from the first law:

[tex]\Delta Q = \Delta U + W[/tex]

After one complete cycle, there is no change in internal energy of the gas so:

[tex]\Delta Q = W[/tex]

This means that the heat flow into the gas minus the heat flow out of the gas equals the work done by the gas:

[tex]\Delta Q = Q_h - Q_c = W[/tex]

Since efficiency is Output/Input

[tex]\eta = W/Q_h = (Q_h - Q_c)/Q_h = 1 - \frac{Q_c}{Q_h}[/tex]

AM
 
Thanks Andrew, I get the overall idea that you want to measure the ratio of heat lost to heat gained. I was running into confusion because, as you stated QH is positive and QC is negative. If I used this convention then the efficiency equation would give a value greater than 1...

So would it not be more accurate to say that QH is the heat put into the system, and QC is the heat expelled by the system, and so both quantities are treated as positive?
 
danrochester said:
Thanks Andrew, I get the overall idea that you want to measure the ratio of heat lost to heat gained.
Efficiency is not a measure of heat lost to heat gained. It is a measure of the rate of work done to heat energy supplied. The heat lost is the heat delivered to the cold reservoir. So efficiency is a measure of the rate at which the heat is NOT lost to the cold reservoir to the heat supplied.

So would it not be more accurate to say that QH is the heat put into the system, and QC is the heat expelled by the system, and so both quantities are treated as positive?
Qc and Qh refer to the magnitude of the heat flows to/from the reservoirs to the engine. If that is all you are saying, you are correct.

AM
 
Last edited:
giordanus and mason are both right, since w=qh-qc, the efficiency(e)=Weng/Qh,

e=1-(Qh/Qc)
 

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