Change in Entropy of an expanding gas

AI Thread Summary
The discussion revolves around calculating the change in entropy of an ideal gas expanding at constant temperature, specifically when its pressure is halved. The key equation for entropy change is ΔS = Q/T, where Q equals work done (W). Participants highlight that knowing the pressure ratio allows for determining the volume ratio, which is crucial for applying the entropy formula. There is also mention of the assumption that the expansion is reversible, which affects the calculations. The conversation emphasizes the importance of understanding the relationships between pressure, volume, and temperature in thermodynamic processes.
Chase11
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Homework Statement


Four moles of an ideal gas expands at constant temperature until its pressure is reduced to half of its initial value. What is the change in entropy of the gas?


Homework Equations


ΔS=Q/T (For constant T) pinitial=p pfinal=.5p
Q=W
W=pdv
nrTln(vf/vi)


The Attempt at a Solution


I tried using nrTln(vf-vi), but realized I can't do that not knowing the temperature or the volumes. Is there an equation using deltap that I could use to solve for this that I am unaware of or can't figure out? Thanks
 
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Chase11 said:

Homework Statement


Four moles of an ideal gas expands at constant temperature until its pressure is reduced to half of its initial value. What is the change in entropy of the gas?


Homework Equations


ΔS=Q/T (For constant T) pinitial=p pfinal=.5p
Q=W
W=pdv
nrTln(vf/vi)


The Attempt at a Solution


I tried using nrTln(vf-vi), but realized I can't do that not knowing the temperature or the volumes. Is there an equation using deltap that I could use to solve for this that I am unaware of or can't figure out? Thanks
The problem statement says the the temperature is constant. So PV= constant. So, if you know the ratio of the initial and final pressures, you also know the ratio of the initial and final volumes. Please note also that you have implicitly assumed that the expansion is reversible.

Chet
 
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General formula for change in entropy is given as
S2 - S1 = CV[ln(T2 / T1) - ln(V2 / V1)] + CPln(V2/V1)
 
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