Change in entropy of an ideal gas during thermodynamic cycle

AI Thread Summary
The discussion focuses on the thermodynamic cycle of an ideal gas, detailing three steps: isochoric heating, adiabatic expansion, and isobaric compression. Participants are tasked with creating a PV diagram and calculating the entropy change for each step, ultimately aiming to demonstrate that the total entropy change for the entire cycle is zero. The conversation highlights the need to express heat capacities in terms of the adiabatic index and the relationships between pressures and volumes during the adiabatic expansion. Clarifications are sought regarding the conditions that must be met for the pressures and volumes involved. The overall goal is to understand the implications of the second law of thermodynamics in this context.
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Homework Statement


An ideal gas with adiabatic index γ is taken around a complete thermodynamic cycle consisting of three steps. Starting at point A, the pressure is increased at constant volume V1 from P1 to P2 at point B. From point B to point C, the gas is allowed to expand adiabatically from volume V1 and pressure P2 to volume V2 and the original pressure P1. Finally, from point C to point A, the volume of the gas is decreased at constant pressure P1 back to the original volume V1.

a) Make a PV diagram of the complete cycle.

b) For each step of the cycle, determine the change in the entropy of the gas. Sum your results to find the total entropy change for the whole cycle. Note that every step is reversible.

c) Use the adiabatic relations to eliminate the pressure from your result for part b. Show that the resulting expression gives a total entropy change for the complete cycle equal to zero.

Homework Equations


ΔS = CP*ln(V/V0) + CV*ln(P/P0)

The Attempt at a Solution


I did part a.) which is in the attachment, as well as my work so far for part b.). I'm not sure how to express the heat capacities in terms of the adiabatic index... any hints?
 

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What you have is correct so far. How do P1, P2, V1, and V2 have to be related for the adiabatic expansion?
 
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