Change in thermal energy of gas

AI Thread Summary
The discussion revolves around calculating the change in thermal energy of a gas compressed from 600 cm³ to 200 cm³ at a constant pressure of 400 kPa, with 100 J of heat energy removed. The correct approach to determine the change in thermal energy is to use the first law of thermodynamics, expressed as ΔE = Q - W. The user initially calculated the work done incorrectly and arrived at 160 J, leading to confusion about the signs of Q and W. After clarification, it was concluded that the change in thermal energy is -60 J, indicating a decrease in temperature. The conversation emphasizes the importance of understanding the signs in thermodynamic equations.
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Homework Statement


A gas is compressed from 600cm3 to 200cm3 at a constant pressure of 400kPa . At the same time, 100J of heat energy is transferred out of the gas.

What is the change in thermal energy of the gas during this process?

Homework Equations


Express the answer in Joules.

Wgas=p(Vf-Vi)=p/\v


The Attempt at a Solution



400k(400cm.3)=p/\v

I came up with a wrong answer of 160 J. Any help would be appreciated.

Thanks,
Jared
 
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You calculated the work done on the gas not the change in thermal energy. What equation gives you the change in thermal energy of a gas?
 
I found the correct equation to use is Eth=Q-Wgas.

Alright. Eth=100J-160J = 60 J is that answer required to be in a positive or negative 60J?

Thanks,
Jared
 
Last edited:
Using the first law is the correct thing to do. It says ΔE = Q - W. You need to pay attention to the symbols and their signs. Is Q positive or negative? What about W? Positive or negative and why?
 
BTW, the sign on W is purely arbitrary. Thermodynamics has adopted the convention that W should be considered from the point of view of the gas: that is, the work done by the gas is W.
 
I am pretty certain the answer is -60J. Although, I don't feel confident that you can have a negative thermal energy change.

@ideasrule- I don't quite understand what you mean?
 
Remember that the internal energy depends on the temperature only. A negative thermal energy change means that the temperature drops.
 

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