Vc can't be just anything. Vc depends on what's inside the box.
If the circuitry in the box is represented by its Thevenin equivalent: a voltage source Vth in series with a resistance Rth, then Vc = Vth - 2*Rth.
A combination of a current source in series with a resistor and a voltage source behaves just like the current source alone. Vc won't depend on the 2Ω resistor and the 5V source; it depends only on what's in the box; not only is the 5V source irrelevant, so is the 2Ω resistor.
If nothing is in the box, just a pair of terminals hanging in the air, then Vc→∞, and Vc will be whatever it takes to sustain the arc across the terminals.
For some really kinky circuit elements, see:
http://en.wikipedia.org/wiki/Norator
http://en.wikipedia.org/wiki/Nullator
http://en.wikipedia.org/wiki/Nullor