desta41 said:
I appreciate your expanding on this matter. I feel as if I have a better understanding.
So would it be fair to say, then, that, thermal radiation from an object (not from an ideal blackbody) has little or nothing to do with electrons jumping or changing energy levels in an atom? It would be all or mostly from rotation and vibration of molecules (which, of course, involves the altered arrangement of electrons and protons)?
Question #2: Let's take a brick in the sunlight. If you were to say that it's the molecules of the brick that absorb the photons, couldn't it be said that, technically, the electrons are absorbing them as well since the molecules contain electrons?
Unfortunately, this is a very common theme here in this forum, and it requires another explanation why we have such a field of study as solid-state physics and condensed matter physics.
When atoms and molecules are clumped together into a solid, they form a conglomerate in which the characteristics of the solid are predominately due to the
collective behavior of all these atoms and molecules. What that means is that the individual behavior of the atoms and molecules are often no longer apparent in the properties of the solids.
One important emergent, collective property that a solid has that are not found in isolated atoms and molecules is presence of
phonons. This is a vibrational modes of a solid due to the gazillion atoms and molecules that make up the solid. In fact, phonons are responsible for a large range of properties of the solid, ranging from optical to thermal to electric transport.
The reason I brought this up is because if you learn solid state physics, and especially the http://www.uni-tuebingen.de/meso/ssscript/phononen.pdf , you will discover that the phonon or vibrational modes have two branches - the acoustic and the optical modes.
The optical modes are "electromagnetically active". It is basically a dipole mode, and this mode can not only absorb EM radiation, but can also, under the right condition, emits EM radiation (it is often called Raman active). This property is often attributed to why we see colors from different objects.
So when you heat, say, a tungsten wire in an incandescent light bulb, if you look at the spectrum using the spectroscope that we give students in many intro physics laboratory, you will see a
continuous spectrum of color, instead of a set of discrete lines that is expected from atomic transition. The heat causes all these vibrational modes of a solid to be enhanced to the point where the EM radiation they emit is intense enough to be seen. This is why the spectrum of light given off is different than from atomic gasses.
Moral of the story here: More Is Different (Phil Anderson)!
Zz.