Dry ice substituting for liqud nitrogen?

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Discussion Overview

The discussion revolves around the feasibility of using dry ice as a substitute for liquid nitrogen in experiments involving superconductors, specifically YBa2Cu3O7. Participants explore the temperature requirements for achieving superconductivity and suggest alternative sources for liquid nitrogen.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested
  • Homework-related

Main Points Raised

  • One participant describes an experiment involving YBa2Cu3O7 and its levitation above liquid nitrogen, expressing difficulty in obtaining liquid nitrogen due to lack of suitable containers at their school.
  • Another participant notes that dry ice, which has a temperature of around 195 K, is not cold enough to reach the superconducting temperature required for YBa2Cu3O7, which is around 90 K.
  • Some participants suggest contacting local universities or hospitals for access to liquid nitrogen, indicating that it is not difficult to transport in small amounts.
  • There are mentions of other potential sources for liquid nitrogen, including welding supply companies and tire recycling plants.
  • Several participants clarify the temperatures associated with nitrogen, correcting earlier statements about melting and boiling points, with some noting the importance of safety when handling liquid nitrogen.
  • One participant proposes an experiment involving liquid nitrogen and pyrolytic carbon, speculating on its properties at low temperatures.

Areas of Agreement / Disagreement

Participants generally agree that dry ice is insufficient for achieving the necessary temperatures for superconductivity in YBa2Cu3O7. However, there is no consensus on the best method to obtain liquid nitrogen, as various suggestions are made without a definitive solution being established.

Contextual Notes

There are unresolved details regarding the specific temperature requirements for superconductivity and the practicalities of sourcing liquid nitrogen. Some participants correct each other on the technical specifications of nitrogen's phase changes, indicating a need for clarity in definitions.

Who May Find This Useful

This discussion may be useful for students and educators involved in chemistry or physics experiments, particularly those exploring superconductivity and the practicalities of using cryogenic materials.

majinknight
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Liquid Nitrogen and Dry Ice

Hi I am doing an experiment for my chemistry independent project which is on doing super conductors, well i am doing one wherre you take YBa2Cu3O7 - the so-called "1-2-3" superconductor and put it in liquid nitrogen and it makes a rare Earth magnet levitate above it, well i have the yittrium barrium copper oxide but i am having trouble getting liquid nitrogen as my school does not have a container to hold it. So i was wondering if dry ice can be substituted instead of liquid nitrogen as the school can get that easily. Thanks!
 
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At temperatures below 195 K (-78 °C), carbon dioxide condenses into a white solid called dry ice.

Liquid nitrogen = 63.15 K (-210.00 °C, -346.00 °F).

The record for maximum Tc is still held by a cuprate perovskite material (Tc = 138 K, that is −135 °C), so dry ice is not cold enough.

http://en.wikipedia.org/wiki/High-temperature_superconductor

Perhaps one could make arrangements with a local university physics/chemistry department, one that has a cryogenics facility.
 
Dry ice isn't anywhere near cold enough to get the YBa2Cu3O7 to the superconducting temperature, which I think is somewhere around 90K. Dry ice, by contrast, is around 195K. You're going to have to get some LN2.

Have your teacher contact a local university physics or chemistry department. They would probably be willing to lend some LN2 and a suitable container.
 
Hospitals, welding supply companies --- you might get lucky and find someone willing to donate time and material.
 
LN2 really isn't that expensive or difficult to transport in small amounts. My dad used to bring home 30 gal jugs of it to give demos for schools. See if you can find someone who works for an industrial gas company - or someone who uses a lot, like Bystander suggested.
 
Astronuc said:
Liquid nitrogen = 63.15 K (-210.00 °C, -346.00 °F).

Minor quibble - that's the melting point of nitrogen. The boiling point is 77K.
 
rachmaninoff said:
Minor quibble - that's the melting point of nitrogen. The boiling point is 77K.
That's what he was referring to, the melting temperature (he was referring to the solid form).

Any biology department is also likely to have people with liquid nitrogen on-hand. It's frequently used to rapidly freeze and store cells or tissues.

Be very careful when using it...you don't want to get ANY on your skin, because it will freeze skin immediately. Wear proper safety goggles and use tongs or some other holder to handle anything being placed in the liquid nitrogen.
 
Another place you can find liquid nitrogen is at a tire recycling plant.
 
rachmaninoff said:
Minor quibble - that's the melting point of nitrogen. The boiling point is 77K.
You are correct - my mistake. Nuts!

It should be the boiling point. 77.36 K (-195.79 °C, -320.42 °F)
 
  • #10
It would be a nice experiment using Liquid Nitrogen on Pyrolytic Carbon, Which already levitates on strong Magnets at room temperature.

I have heard no word of its properties at Liquid Nitrogen Temperatures.

I smell a Noble Prize around here somewhere.:smile:
 

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