Effect of specific heat of a substance on the rate of heat flow

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Discussion Overview

The discussion revolves around the effect of specific heat capacity on the rate of heat flow between substances. Participants explore whether specific heat capacity influences heat transfer rates when substances are at the same temperature and left to reach thermal equilibrium. The scope includes theoretical considerations and conceptual clarifications related to heat transfer principles.

Discussion Character

  • Debate/contested
  • Conceptual clarification
  • Technical explanation

Main Points Raised

  • One participant suggests that a substance with a larger specific heat capacity cools faster due to a greater energy difference with the environment, proposing a relationship between specific heat and heat flow rate.
  • Another participant counters that temperature difference, rather than energy difference, is crucial for heat flow, emphasizing that materials with higher heat capacity resist temperature changes more effectively.
  • A different participant asserts that heat capacity does not affect heat flow, claiming that the heat transfer coefficient is the primary factor influencing heat transfer rates.
  • One participant elaborates on the distinction between instantaneous heat flow and long-term temperature changes, indicating that while instantaneous power does not depend on heat capacity, the overall temperature change over time does require consideration of heat capacity.

Areas of Agreement / Disagreement

Participants express differing views on the role of specific heat capacity in heat flow, with no consensus reached. Some argue that it is significant, while others maintain that it is not a determining factor, leading to an unresolved discussion.

Contextual Notes

Participants reference various factors affecting heat flow, including temperature difference, geometry of the system, and heat transfer coefficients, but do not reach a unified understanding of how these factors interact with specific heat capacity.

emporia
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I have been wondering, does specific heat capacity affect the rate of heat flow from one substance to another?

For example if the substances at heated up to the same temperature then left outside until thermal equilibrium is reached. I would think the one with the larger specific heat capacity (substance x) cools at a faster rate as the energy difference between it and the atmosphere is greater than the one with a smal specific heat (substance y).

The larger the energy difference the greater the rate of heat flow. As this energy difference becomes smaller due to the substance the rate of flow would lessen.

The rate of heat flow behaves similarly to an exponential funtion, therefore am i correct in assuming that the affect of specific heat on heat flow is offset by the decrease of the energy difference effectively cancelling out the effect of specific heat?
 
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Energy difference isn't what is important. Temperature difference is. Surface area is. All things being equal, the material with the greatest heat capacity will resist a change in temperature more so than one with a small heat capacity.

That is kind of the definition of heat capacity, y'know.
 
emporia said:
I have been wondering, does heat capacity affect the rate of heat flow from one substance to another?

No. Heat transfer coefficient is the only thing that counts.
 
Borek said:
No. Heat transfer coefficient is the only thing that counts.

Thanks for that.
I'm just puzzled now that my chemistry teacher agreed with me on the previous explanation but was doubtful when i suggested that heat capacity doen't affect heat flow.
 
Well... there is a heat flow and there is a heat flow :wink:

Say you have two bodies of different temperatures. Net heat flow is that from the hotter body to the colder body. Amount of the the heat that flows in the time unit is just a power - and this power doesn't depend on the heat capacity, in any given moment it depends on the temperature difference, geometry of the system and heat capacity coefficient. Period.

Now, if you are interested not in in a situation at any given time point, but in the changes of the temperature in a long period of time, knowing just power transmitted in any moment is not enough. You have to account for heat capacity of the system, as it will change the speed at which temperature of the different parts of the system will change - changing heat flow (power).
 

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