Electroplating Experiment: Calculating Copper Mass from Silver Deposition

In summary, during an electroplating experiment, 21.6 g of silver is deposited by passing the same amount of electricity through 1.00 L of a 1.00 mol/L CuSO4(aq) solution. Using Faraday's law of electrolysis, the total electric charge can be found, which can then be used to calculate the mass of copper deposited. Since the valence of copper in CuSO4 is 2+, it is necessary to use a factor of 2 in the equation.
  • #1
dav1d
65
0

Homework Statement



Exactly 21.6 g of silver is deposited during an
electroplating experiment. The same amount of
electricity is passed through 1.00 L of a 1.00 mol/L
CuSO4(aq) solution. What mass of copper is
deposited?
Relative atomic masses:
Ag 107.87; Cu 63.55

Homework Equations





The Attempt at a Solution



I really have no idea how to do this.
 
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  • #2
Do you know Faraday's law of electrolysis?
 
  • #3
No, never heard of it. Can you link me to it?
 
  • #5
m=(Q/F)(M/z)

m is the mass of the substance liberated at an electrode in grams
Q is the total electric charge passed through the substance
F = 96,485 C mol−1 is the Faraday constant
M is the molar mass of the substance
z is the valency number of ions of the substance (electrons transferred per ion).


so

Q:how do i find the total charge? Only given The same amount of
electricity is passed

F=const
M: 63.55
z=1 or 2?
 
  • #6
What reactions are taking place during electrodeposition of both metals? What is z?

Come on, show some effort, so far you are just asking for help on each step. We can help, we can't spoonfeed you.
 
  • #7
I just don't really understand.

Redox is happening during the electrodeposition? Z is the valence number but copper is multivalent so it can be 1 or 2?

wait

Can't you just rearrange the equation for Q, plug in the 21.6 grams from aluminum and then find the Q?
Then redo the equation with Q solved for and then plugin everything else, F=const, M=unkown, and then Z still is 1 or 2?
 
  • #8
No idea where did you got aluminum from. But yes, you have to find the charge from known amount of reduced silver.

You are specifically told to use CuSO4, what is the valence of the copper in this compound?
 
  • #9
Exactly 21.6 g of silver is deposited during an
electroplating experiment. The same amount of
electricity is passed through 1.00 L of a 1.00 mol/L
CuSO4(aq) solution.

It should be 2+ for the Cu correct?
 
  • #10
dav1d said:
It should be 2+ for the Cu correct?

Yes.
 

1. How does electroplating work?

Electroplating is a process in which a metal ion in a solution is reduced and deposited onto a conductive surface, typically through the application of an electric current.

2. What materials are needed for an electroplating experiment?

The materials needed for an electroplating experiment include a conductive surface (such as a metal object), a solution containing the metal ion to be deposited, an anode (positive electrode), a cathode (negative electrode), and a power source.

3. How do you calculate the mass of copper deposited during an electroplating experiment?

The mass of copper deposited can be calculated by multiplying the current (in amperes), the time (in seconds), and the electrochemical equivalent of copper. The electrochemical equivalent of copper can be found in a table or calculated using the atomic weight of copper and Faraday's constant.

4. What is the purpose of using silver as the source of the metal ion in an electroplating experiment?

Silver is often used as the source of the metal ion because it has a higher reduction potential than copper, meaning it can be reduced more easily and deposited onto the cathode. This allows for a more efficient and controlled deposition of copper.

5. Are there any safety precautions to keep in mind when conducting an electroplating experiment?

Yes, it is important to wear protective equipment (such as gloves and goggles) and follow proper handling and disposal procedures for the chemicals used in the experiment. It is also important to properly set up and monitor the power source to prevent any accidents.

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