Is a system always at equilibrium during phase changes?

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The discussion centers on the concept of Gibbs Energy in relation to phase changes in chemistry. It highlights that at the boiling point, the system is at equilibrium with deltaG equal to zero and deltaH equal to TdeltaS. Participants agree that the system is indeed at equilibrium during any phase change, not just at the boiling point, as the free energies of the different phases are equal at the phase boundaries in the phase diagram. This indicates that equilibrium is a fundamental characteristic of phase transitions.
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I am in the section of Gibbs Energy for my chemistry course and in the textbook it says the system is at equilibrium at the boiling point, so deltaG=0, and deltaH=TdeltaS. I was just wondering if the system is always at equilibrium during any phase change, not just at its boiling point.

Thanks!
 
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reconrusty said:
equilibrium during any phase change
The free energies of the phases are equal at the phase boundaries in the phase diagram, so what do you think?
 
I should say yes.
 
Fair 'nuff.
 
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