Heat capacity of water -- experimental determination

Click For Summary

Homework Help Overview

The discussion revolves around the experimental determination of the heat capacity of water, particularly focusing on the transition from ice to liquid water as it warms in a controlled environment. The original poster presents data collected from a cooling and warming experiment involving water in a beaker, aiming to analyze the heat transfer and phase changes occurring during the process.

Discussion Character

  • Exploratory, Conceptual clarification, Mathematical reasoning

Approaches and Questions Raised

  • The original poster attempts to relate the power delivered to the system with the heat capacities of ice and water using experimental data. They question how to derive absolute values for heat capacities from the ratios obtained and seek clarification on the quantitative results that can be deduced from their observations.

Discussion Status

Some participants seek clarification on the specific questions posed in the homework statement, while others provide insights into the nature of heat transfer during the phase change and the implications for calculating heat capacities. There is an ongoing exploration of the relationships between the observed data and the theoretical concepts involved.

Contextual Notes

Participants note the constraints of the problem, including the inability to determine absolute heat capacities and the focus on ratios between the heat capacities of ice and liquid water. The original poster also emphasizes the need to explain the general form of the experimental results as part of their assignment.

sunquick
Messages
18
Reaction score
0

Homework Statement


A quantity of water in a beaker of negligible thermal capacity is cooled to a few degrees below freezing point. The beaker is then placed in a warm room, and the times recorded at which it is at various temperatures as it gradually warms. The observations were:

temperature/ºC time/min:
-3.0 0
-2.0 0.93
-1.0 1.89
0 2.92
...
0 169.72
1.0 171.84
2.0 174.04
3.0 176.34

Homework Equations


Q=C \Delta T
Q= L
Q= P \Delta t

The Attempt at a Solution



My question concerns part b)
I assume the power delivered to the system is constant.
So Q=C \Delta T = P \Delta t or
\frac{\Delta t}{\Delta T} = C/P = const

So I fit a straight line to the experimental points to determine the slope and so to know C/P.
There will be two heat capacities, one for ice and the other for liquid water. I can determine the ratio o C_ice / C_water, and also of the latent heat necessary to melt the ice by noting that

P \frac{\Delta t_1}{\Delta T} = C
P \Delta t_2 = L
\Delta t_2 \frac{\Delta T}{\Delta t_1} = L / C

I can find the heat capacities and latent heats with respect to one another, but I can't seem to know how find one of them in "absolute terms". My question is if that is possible, and what other quantitative results can be obtained from the observations?
 
Physics news on Phys.org
Please state exactly what the question asks for.
 
Sorry I forgot tho type that part of the problem:

a) Explain the general form of the experimental results.
b) What quantitative results can you deduce from the observations?

For part a) I have to explain that heat is transferred to the ice, increasing its temperature, till it reaches 0ºC. Then it stays at that temperature until all the ice has melted away, because all the heat entering the system is going into changing the phase of the water instead of increasing its temperature. Once the ice has melted, the temperature rises again, this time at a different rate than before because water has a different specific heat capacity than ice.
 
sunquick said:
Sorry I forgot tho type that part of the problem:

a) Explain the general form of the experimental results.
b) What quantitative results can you deduce from the observations?

For part a) I have to explain that heat is transferred to the ice, increasing its temperature, till it reaches 0ºC. Then it stays at that temperature until all the ice has melted away, because all the heat entering the system is going into changing the phase of the water instead of increasing its temperature. Once the ice has melted, the temperature rises again, this time at a different rate than before because water has a different specific heat capacity than ice.
Then I think you are finished. As you say, you cannot determine the heat capacities of the water sample in its different phases, let alone the capacities per unit mass. All you can provide is the ratios between them.
 

Similar threads

  • · Replies 6 ·
Replies
6
Views
1K
  • · Replies 3 ·
Replies
3
Views
2K
  • · Replies 9 ·
Replies
9
Views
3K
  • · Replies 5 ·
Replies
5
Views
2K
  • · Replies 17 ·
Replies
17
Views
6K
  • · Replies 9 ·
Replies
9
Views
2K
  • · Replies 6 ·
Replies
6
Views
3K
Replies
7
Views
2K
  • · Replies 2 ·
Replies
2
Views
2K
  • · Replies 2 ·
Replies
2
Views
5K