Heat is just kinetic energy at a molecular level, right?

In summary, the velocity of particles at a given temperature can be determined using the equipartition theorem, which relates the temperature and velocity through the equation 3*1/2kT = 1/2 mv2. However, this only gives the root mean square (rms) velocity of the particles and does not take into account individual velocities at different points in time. Additionally, the density and packing density of molecules can also affect the velocity of particles.
  • #1
LastTimelord
32
0
Assuming a density of exactly 1 g/cm3 (assuming that even matters)

So, at 1 kelvin, how fast do the molecules actually move? Is it a direct, or exponential increase to 2 kelvin?

This might be a stupid question. I'm not a scientist.
 
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  • #2
LastTimelord said:
Assuming a density of exactly 1 g/cm3 (assuming that even matters)

So, at 1 kelvin, how fast do the molecules actually move? Is it a direct, or exponential increase to 2 kelvin?

This might be a stupid question. I'm not a scientist.

Density does not matter. Relating macroscopical phenomena of thermodynamic equilibrium to atomic level events was subject to much research and is legitimate scientific question. Quick was to relate temperature and velocity of a particle is through equipartition - let say you have pointlike atoms. For every degree of freedom - number of independent ways particle can move - you get 1/2kT of kinetic energy. Such particle has 3 degrees of freedom, so

3*1/2kT = 1/2 mv2

where k is Boltzmann constant, T is temperature in kelvins, m is mass of a particle and v is the thing you are interested in - velocity of a particle.
 
  • #3
The previous post is correct in the equation given; however, the density is actually useful but we need one more piece of information, the packing density of molecules (i.e. number of molecules per unit volume). With that number, you can determine the mass of of an individual molecule and thus the velocity.

Regardless, it's clear from the equation that velocity increases as the square root of temperature. So increase the temperature by a factor of 100, the velocity increases by a factor of 10.
 
  • #4
This equation is very helpful, but what would the unit of velocity be in this case?
 
  • #5
xlines said:
Density does not matter. Relating macroscopical phenomena of thermodynamic equilibrium to atomic level events was subject to much research and is legitimate scientific question. Quick was to relate temperature and velocity of a particle is through equipartition - let say you have pointlike atoms. For every degree of freedom - number of independent ways particle can move - you get 1/2kT of kinetic energy. Such particle has 3 degrees of freedom, so

3*1/2kT = 1/2 mv2

where k is Boltzmann constant, T is temperature in kelvins, m is mass of a particle and v is the thing you are interested in - velocity of a particle.

Just to be very clear, the equipartition theorem does not give you the velocity of a single particle, it gives you the root mean square (rms) velocity of the atoms of an ideal gas in thermal equilibrium at temperature T. In this case, where all of the atoms are the same (i.e., have the same mass and are classical particles), it follows that this is the rms velocity of a single atom, but that atom could at times be going much faster or much slower than the rms velocity.

That is to say, temperature is related to the average kinetic energy.

Also, it's worth noting that when one asks how the rms velocity increases with temperature, the word "increases" is a bit misleading. The equipartition theorem relates, for example, the rms velocities and temperatures of two systems in equilibrium, but it only relates the rms velocities and temperatures of a single system at different points in time when the system is in thermal equilibrium at those two points in time.

That is, you can use it relate the rms velocity of a system in equilibrium at temperature ##T_1## at time ##t_1## compared to its rms velocity at a later time ##t_2## and temperature ##T_2##, but only so long as you have waited for the system to settle back down into equilibrium. The equipartition theorem does not hold while you are heating the system from temperature ##T_1## to ##T_2##; i.e., while the temperature is actually increasing - hence why I say "increasing" is a misleading word to use.

So, you can relate the rms velocities and temperatures of two different systems in equilibrium, or you can relate the rms velocities and temperatures of a single system that is in equilibrium at different temperatures at different points in time, but you can't do that while you are actually physically increasing the temperature.
 

1. How is heat related to kinetic energy at a molecular level?

Heat is directly related to the kinetic energy of molecules. When molecules are in constant motion, they possess kinetic energy. As the temperature of a substance increases, the molecules move faster and their kinetic energy increases, resulting in the substance feeling hotter.

2. What is the difference between heat and temperature?

Heat and temperature are often used interchangeably, but they are not the same thing. Temperature is a measure of the average kinetic energy of molecules in a substance, while heat is the transfer of energy from one object to another due to a temperature difference. In other words, heat is a form of energy, while temperature is a measure of the amount of energy present.

3. Is heat the only form of energy at a molecular level?

No, heat is just one form of energy at a molecular level. Atoms and molecules also possess potential energy, which is stored energy due to their position or arrangement. In addition, there are other forms of energy at a molecular level, such as electromagnetic energy and nuclear energy.

4. How does heat transfer occur at a molecular level?

Heat transfer at a molecular level occurs through three main mechanisms: conduction, convection, and radiation. In conduction, heat is transferred through direct contact between molecules. In convection, heat is transferred through the movement of fluids, such as air or water. In radiation, heat is transferred through electromagnetic waves.

5. Can heat be converted into other forms of energy at a molecular level?

Yes, heat can be converted into other forms of energy at a molecular level. This is known as the principle of energy conservation, which states that energy cannot be created or destroyed, but can only be converted from one form to another. For example, heat can be converted into mechanical energy, such as when steam is used to power a turbine.

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