Heat of Evaporation: Melting Ice to Boil Nitrogen

In summary, the ice cube, with a mass of 0.035 kg and a specific heat of 2100 J/kg*C, is dropped into an insulated container of nitrogen, which has a heat of vaporization of 200000 J/kg and is at its boiling point of -196 C. Assuming all of the ice cube's heat energy is used to heat the nitrogen, it is calculated that 0.072 kg of nitrogen will evaporate. However, the problem is incomplete as it does not specify the mass of the nitrogen or its initial temperature, which would affect the final outcome.
  • #1
HaoPhysics
26
0

Homework Statement


A 0.035 kg ice cube at its melting point is dropped into an insulated container of liquid nitrogen. How much nitrogen evaporates if it is at its boiling point of -196 C?

Nitrogen has heat of vaporization of 200000 J/kg
Ice's specific heat is 2100 J/kg*C

Homework Equations


Assuming that all of the ice cube's heat energy is used to heat the nitrogen.
Q = m c T = (0.035)(2100)(0- -196) = 14406 J

Latent Heat for Nitrogen (H)
H = m*L = m*200000

The Attempt at a Solution


Since Q = H

14406 = 200000*m
m = 0.072 kg

This is the correct answer.

But what I do not understand is:

How do we know for sure that the ice cube will reach a temperature of -196 C?
This problem feels incomplete. What if the container of nitrogen had 10^1000000000 kg of nitrogen? What if the nitrogen was at 1 K? Clearly, in some cases, that ice cube will not be able to bring the nitrogen to boil. This is not factored into the solution.
 
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  • #2
There is an unstated premise that there is more nitrogen than ice.
HaoPhysics said:
This problem feels incomplete. What if the container of nitrogen had 10^1000000000 kg of nitrogen?
How would that change the answer?

HaoPhysics said:
What if the nitrogen was at 1 K? Clearly, in some cases, that ice cube will not be able to bring the nitrogen to boil. This is not factored into the solution.
The problem explicitly states that the nitrogen is at its boiling point. Can you see why this is a necessary condition for you to arrive at an answer? Would information would be missing if the initial temperature was lower?
 
  • #3
DrClaude said:
There is an unstated premise that there is more nitrogen than ice.

How would that change the answer?The problem explicitly states that the nitrogen is at its boiling point. Can you see why this is a necessary condition for you to arrive at an answer? Would information would be missing if the initial temperature was lower?

Ohhh. I see it now. For some reason I thought the problem simply said, "the generic boiling point of nitrogen is -196 C," and thus was wondering how we knew for sure it would get to -196 C.

If the initial temperature was NOT -196 C, then we would HAVE to know what the mass of nitrogen is to see how much temperature increase occurs correct?
 
  • #4
HaoPhysics said:
If the initial temperature was NOT -196 C, then we would HAVE to know what the mass of nitrogen is to see how much temperature increase occurs correct?
Correct! You would have to discriminate the heat leading to an increase in temperature to that leading to evaporation.
 

1. What is heat of evaporation?

Heat of evaporation, also known as enthalpy of vaporization, is the amount of energy required to transform a substance from its liquid state to its gaseous state at a constant temperature and pressure.

2. Why does melting ice require less energy than boiling nitrogen?

Melting ice requires less energy because it is a phase change from a solid to a liquid, which has a lower heat of fusion compared to the heat of vaporization required for a phase change from a liquid to a gas, as in the case of boiling nitrogen.

3. How is heat of evaporation affected by temperature and pressure?

Heat of evaporation is directly proportional to temperature and inversely proportional to pressure. This means that as temperature increases, the heat of evaporation also increases, and as pressure decreases, the heat of evaporation also increases.

4. What factors can affect the heat of evaporation?

The heat of evaporation can be affected by the type of substance, temperature, pressure, and the strength of intermolecular forces between molecules. Other factors such as impurities and dissolved substances can also affect the heat of evaporation.

5. How is heat of evaporation measured?

The heat of evaporation is typically measured using calorimetry, which involves measuring the amount of heat required to change the phase of a substance at a constant temperature and pressure. This can be done using specialized equipment such as a bomb calorimeter or a differential scanning calorimeter.

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