Heat required at constant pressure

AI Thread Summary
To determine the heat energy required to raise the temperature of a gaseous mixture of 1 gm of Hydrogen and 1 gm of Helium from 0°C to 100°C at constant pressure, the specific heats of both gases were calculated using their respective heat capacities and the universal gas constant. The calculated heat required was 53,200 Joules or 466 Calories, but discrepancies arose due to differing values of the gas constant used in the calculations. The mixture's specific heat should logically fall between the specific heats of Hydrogen and Helium. The discussion highlights the importance of consistent unit usage in thermodynamic calculations. Accurate calculations are essential for obtaining reliable results in heat energy assessments.
Amith2006
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Homework Statement


1) How much heat energy must be added to the gaseous mixture consisting of 1 gm of Hydrogen and 1 gm of Helium to raise its temperature from 0 degree C to 100 degree C
at constant pressure? Given that g1=1.41, g2=1.67



Homework Equations



Heat required = nC(p)dT

The Attempt at a Solution




Heat energy in Joules:

Let C(p1), C(p2) and C(p) be the specific heat of Hydrogen, Helium and the mixture at constant pressure respectively. Let g1,g2 and g be the ratio of the specific heats at constant volume and pressure for Hydrogen, Helium and the mixture respectively. Here I have taken the value of the universal Gas constant[R] = 8.314 Joule/mole-K
C(p1) = (g1 x R)/(g1 -1)
= 28.59 J/mole-K
C(p2) = (g2 x R)/(g2-1)
= 20 .72 J/mole-K
C(p) = {(n1 x C(p1)) + (n2 x C(p2))}/(n1 + n2)
= 709.7 J/mole-K
Let n1,n2 and n be the number of moles of Hydrogen, Helium and the mixture respectively.
n1 = 0.5 moles
n2 = 0.25 moles
n = 0.75 moles
Heat required = nC(p)dT
= 53200 Joules = 12666 Calories

Heat energy in Calories:

Here I have taken the value of the universal Gas constant[R] = 1.99 Calorie/mole-K
Heat required = 466 Calories
Why do I get 2 different answers just because of change in units of R?
 
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Because your C(p) = 709.7 can't possibly be right. If the components have Cp of 28.59 and 20.72, the mixture must have Cp in between those values.

The equation looks OK, so I guess you hit the wrong buttons on your calculator.
 
U r right. What am I doing??Thanks.
 
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