Sounds like this could be dangerous, assuming this is North American 220, which is 110-neutral-110. If you get 220 from one of lines to the chassis, that could indicate the chassis is sitting near 110 volts of the other leg. But also, voltmeters are very high impedance, a little leakage current could provide a high voltage reading.
But, the chassis should be grounded, so very near the neutral in potential. Each leg should measure 110V to neutral, and 110 V to the chassis.
It is sometimes helpful to repeat that with a 110V filament bulb (25W, 40 W 60W, no matter) across the meter leads to provide a load.
I had an electric stove top with some burnt food that bridged from one hot line to the chassis, and it turned out the chassis was not grounded. We were getting shocks from the chassis until I investigated, grounded the stove, and when I turned the breaker back on - POW! - the burnt food blew out from the rush of current.
No more shocks though.