How to determine dsp2 or sp3 structure?

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However, there may be exceptions to this rule depending on the specific ligands and their bonding interactions with the central metal ion.
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sachin123
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Taking an example as:
[CuCl4]2- (charge =-2)
I finding it very confusing to decide whether the structure would be dsp2 or sp3?
There will 9 electrons in d orbital of Cu2+ in this compound.
In the presence of Cl- ligand will one electron get transferred to 4p orbital or will it stay in the 3d orbital?More importantly why would it behave so?
I just want a general rule so I won't have to mug up all the compounds.My textbook doesn't give any extra information.
Please help me out.
Thank you
 
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.The structure of [CuCl4]2- is sp3 because it has a tetrahedral coordination geometry. The four chlorine atoms occupy the four positions in the tetrahedron, and the copper ion is at the center. The nine electrons in the d orbital of Cu2+ will remain in the 3d orbital. The explanation for this is that the 3d orbitals are more stable than the 4p orbitals, so electrons prefer to stay in the 3d orbitals rather than being transferred to the 4p orbitals. This is a general rule that applies to most transition metal complexes.
 

Related to How to determine dsp2 or sp3 structure?

What is the difference between dsp2 and sp3 structures?

The main difference between dsp2 and sp3 structures is the number of hybrid orbitals used. A dsp2 structure involves the use of d, s, and p orbitals, while an sp3 structure only involves s and p orbitals.

What factors determine whether a molecule has a dsp2 or sp3 structure?

The main factor that determines whether a molecule has a dsp2 or sp3 structure is the type of bonding that occurs. If the molecule has multiple bonds or lone pairs of electrons, it is more likely to have a dsp2 structure. On the other hand, if the molecule has only single bonds, it is more likely to have an sp3 structure.

How can I determine the structure of a molecule?

To determine the structure of a molecule, you can use various techniques such as X-ray crystallography, nuclear magnetic resonance (NMR) spectroscopy, and computational methods. These techniques provide information about the bonding and geometry of the molecule, which can help determine its structure.

What is the significance of knowing the structure of a molecule?

Knowing the structure of a molecule is important because it provides information about its physical and chemical properties, reactivity, and potential uses. It also helps in predicting how the molecule will interact with other substances and how it will behave in different environments.

Can a molecule have both dsp2 and sp3 structures?

No, a molecule can only have one type of structure at a given time. However, some molecules can exhibit resonance, where the electrons are delocalized and the molecule has multiple possible structures. In these cases, the molecule can be described as a hybrid of the different structures.

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