Suppose you had a vector with x component +2 and y component +2. If you use the arctan function on your calculator to find the angle, you get ##arctan(\frac{+2}{+2}) = arctan(1)= 45^o##. This is correct for the angle as measured counterclockwise from the positive x axis.
In your case, you have a vector with x component -2 and y component -2. Your calculator gives ##arctan(\frac{-2}{-2}) = arctan(1)= 45^o##. This is not the correct angle as measured from the positive x axis. You can see why your calculator can't handle this correctly since it naturally treats ##\frac{-2}{-2}## as identical to ##\frac{+2}{+2}##. In other words, your calculator's arctan function can't tell the difference between a vector in the first quadrant and a vector in the third quadrant. Likewise, it can't distinguish between a vector in the 4th quadrant and vector in the 2nd quadrant.
Generally, your calculator will give the correct answer for vectors in the 1st and 4th quadrants. For the 2nd and 3rd quadrants, adding 180 degrees to what your calculator gives you will give the correct answer for the angle as measured counterclockwise from the positive x-axis. For example, in your case, your calculator gave an answer of 45 degrees. But a rough sketch of the vector shows that it is in the third quadrant. If you add 180 to 45 you get 225 degrees as measured counterclockwise from the positive x axis; or, as they say, 225 degrees "above the x axis". You can see that this is the same as 135 degrees "below" the x-axis (i.e., 135 degrees clockwise from the positive x axis.)
To be safe, it is always a good idea to draw a sketch of the vector. Then you can construct your own right triangle on the sketch and use simple trig on the triangle to find the direction of the vector.