Irreversible Adiabatic Expansion (Physical Chemistry)

AI Thread Summary
The discussion focuses on calculating the final temperature of an ideal monatomic gas undergoing irreversible adiabatic expansion. Given the initial conditions of pressure and temperature, the user needs to determine the change in temperature (ΔT) but is initially unsure how to find the change in volume (ΔV). The solution involves using the ideal gas law to express the final volume in terms of the final temperature and substituting this into the equation for ΔT. After rearranging and solving the resulting equation, the final temperature can be determined. The process requires careful algebraic manipulation to isolate the final temperature.
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Homework Statement


Consider the adiabatic expansion of .553mol of an ideal monatomic gas with CV,m = 3R/2. The initial state is described by P = 6.25bar and T = 306K. Calculate the final temperature if the same gas undergoes an adiabatic expansion against an external pressure of P = 1.25bar to a final pressure P = 1.25bar.


Homework Equations


CVΔT = -PextΔV


The Attempt at a Solution


I need to find ΔT. P, V, and T are all variables, though, so I can't find ΔT because I don't know ΔV. What do I do?
 
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Use the ideal gas law to express the final volume algebraically in terms of the final temperature. Substitute this into your equation. The final temperature will be on both sides of the resulting equation. Collect terms involving the final temperature, and solve for it.
 
A little bit of annoying algebra, but I got it. Thank you very much.
 
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