It seems redundant to use the product and chain rules together. For an equation like this one it is much simpler to just use the general power rule for derivatives:
\frac{d}{dx}xr=rxr-1
In general the chain and product rules are only used when there are distinct functions f(x) and g(x). Doing what rygza is suggesting (though it gives you the correct answer) assumes f(x)=5 and g(x)=x1/2 for the product rule portion. But f'(x)=0. Then for the chain rule portion f(x)=5x1/2 and g(x)=x. But g'(x)=1.
So in summary you just do a bunch of extra steps before ending up with d/dx 5x1/2 which requires the power rule to solve (=2.5x-1/2)