Isothermal Expansion of a Diatomic Gas

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Homework Help Overview

The discussion revolves around the isothermal expansion of a diatomic gas, specifically nitrogen, in a piston chamber. The original poster seeks to determine the final temperature after the gas expands from a volume of 0.0500 m3 to 0.150 m3 under a final pressure of 110 kPa.

Discussion Character

  • Exploratory, Assumption checking

Approaches and Questions Raised

  • The original poster attempts to apply the ideal gas law and Boltzmann's constant to find the final temperature but expresses uncertainty about the correct use of the number of particles in the calculations.

Discussion Status

Participants are exploring the relationship between the number of molecules and the number of atoms in the context of the problem. Some clarification has been provided regarding the definition of N as the number of particles, which includes molecules, atoms, and ions.

Contextual Notes

The original poster questions the relevance of initial volume and pressures in their calculations and expresses doubt about the ideal behavior of diatomic gases in this scenario.

MaryCate22
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Homework Statement


A 0.300-kg sample of nitrogen gas (diatomic molecules,mN2 = 4.652 × 10^−26 kg) in a chamber fitted with a piston undergoes an isothermal expansion from 0.0500 m^3 to 0.150 m^3 .

If the final pressure is 110 kPa, what is the final temperature?

Homework Equations


PV=N*kB*T where Boltzmann's Constant is kB=1.38*10^-23 J/K

The Attempt at a Solution


Because the process is isothermal, PV = constant and Ti = Tf.
To use the formula, I need N (number of molecules).

0.300/[(4.652*10^-26)(0.5)]=1.29*10^25

Plugging this N into T=PV/NkB I get, T = 92.7 K, which is not the right answer.

I don't think diatomic gasses behave ideally, but I have no idea how to reflect that in the formula. I also do not know how the initial volume and pressures are relevant.
 
Last edited:
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The question is what is the final temperature if the final pressure is 110 kPa. Sorry, I'll edit.
 
Just a thought, am I supposed to use the number of molecules or the number of atoms?
 
MaryCate22 said:
,mN2 = 4.652 × 10^−26 kg

MaryCate22 said:
0.300/[(4.652*10^-26)(0.5)]=

MaryCate22 said:
am I supposed to use the number of molecules or the number of atoms?
 

Well that clears it up. Thank you.
 
N is the number of particles which can be molecules, atoms, ions etc.
 

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