Electron Domain Geometry vs Molecular Shape

In summary, electron domain geometry and molecular shape are two different concepts that describe the arrangement of electrons and atoms in a molecule. While electron domain geometry is a theoretical concept, molecular shape is a physical observation. The electron domain geometry of a molecule can be determined by counting the number of bonding and non-bonding electron pairs around the central atom, which corresponds to a specific geometry. The electron domain geometry and molecular shape can be different, especially when there are lone pairs of electrons present. The molecular shape of a molecule can affect its physical properties, such as boiling point and polarity, as it determines the type and strength of intermolecular forces. Lastly, there is a direct relationship between electron domain geometry and bond angles, as the number and arrangement
  • #1
Asian Girl
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What's the difference between "Electron Domain Geometry" and "Molecular Shape"?

Please help! Thanks
 
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  • #2
Been http://www.occc.edu/KMBailey/Chem1115/Unit7/Unit7c.ppt#35"
 
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  • #3
From what I remember the electron domain geometry pertains to the arrangment of electrons around the central atom while molecular shape is in reference to the arrangement of bonds around the central atom.

One can be different then the other for instance consider water - its molecular shape is considered bent while its electron geometry is tetrahedral.
 

1. What is the difference between electron domain geometry and molecular shape?

Electron domain geometry refers to the arrangement of electron domains (bonding and non-bonding) around a central atom in a molecule. Molecular shape, on the other hand, describes the actual shape of the molecule, taking into account the arrangement of atoms and lone pairs of electrons. In other words, electron domain geometry is a theoretical concept, while molecular shape is a physical observation.

2. How do you determine the electron domain geometry of a molecule?

The electron domain geometry of a molecule can be determined by counting the number of bonding and non-bonding electron pairs around the central atom. This number will correspond to a specific electron domain geometry, such as linear, trigonal planar, tetrahedral, etc.

3. Can the electron domain geometry and molecular shape be different?

Yes, the electron domain geometry and molecular shape can be different. This can occur when there are lone pairs of electrons on the central atom, which can affect the overall shape of the molecule. For example, a molecule with a tetrahedral electron domain geometry may have a bent molecular shape if there is one or more lone pairs of electrons present.

4. How does the molecular shape affect the physical properties of a molecule?

The molecular shape of a molecule can affect its physical properties, such as boiling point, melting point, and polarity. This is because the arrangement of atoms and lone pairs of electrons can determine the strength and type of intermolecular forces present in the molecule.

5. What is the relationship between electron domain geometry and bond angles?

There is a direct relationship between electron domain geometry and bond angles. The number and arrangement of electron domains around the central atom will determine the bond angles in the molecule. For example, a molecule with a tetrahedral electron domain geometry will have bond angles of approximately 109.5 degrees.

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