Physical Chemistry: Partial Molar Volumes NaCl Solutions

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Partial molar volumes in NaCl solutions refer to the concept that the total volume of a mixture is not simply the sum of the individual volumes of its components. Instead, it can be expressed by the equation V = n1V1 + n2V2, where V is the total volume, n1 and n2 are the moles of each component, and V1 and V2 are the partial molar volumes. This principle highlights how interactions between different substances can affect the overall volume, which is particularly relevant in solutions. The discussion also notes that while the concept was demonstrated through a lab mixing alcohols and water, the underlying principle remains applicable to salt solutions like NaCl.
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I'm actually taking a physical chem course and i have to hand in a report onpartial molar volumes in NaCl solutions...I'm not really sure how the concept works and I'm wondering if anyone could clarify! Thanks
 
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Heh, just did this lab, so let's see if I can help.

The idea with partial molar volumes is that when you mix a certain volume of some substance with a certain volume of another, the total volume in many cases is not simply V(A) + V(B). The total volume can be represented by the equation V~=~n_1\overline{V_1}~+~n_2\overline{ V_2}, where V is the total volume, n1 and n2 are the quantities of the mixture in moles, and V1 and V2 are defined as the partial molar volumes of the components of the mixture.

We mixed alcohols and water, and its a little different for salts, though I suppose the principle is basically the same.
 
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